<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">geores</journal-id><journal-title-group><journal-title xml:lang="ru">Георесурсы</journal-title><trans-title-group xml:lang="en"><trans-title>Georesources</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1608-5043</issn><issn pub-type="epub">1608-5078</issn><publisher><publisher-name>Georesursy LLC</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.18599/grs.2021.4.10</article-id><article-id custom-type="elpub" pub-id-type="custom">geores-167</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ГЕОЛОГИЧЕСКИЕ, ГЕОХИМИЧЕСКИЕ И ГЕОФИЗИЧЕСКИЕ ИССЛЕДОВАНИЯ</subject></subj-group></article-categories><title-group><article-title>К вопросу о дифференциации расплава в промежуточной камере (на примере дифференцированных интрузивов западного склона Южного Урала)</article-title><trans-title-group xml:lang="en"><trans-title>On the melt differentiation in the intermediate chamber (by the example of differentiated intrusives of the western slope of the Southern Urals)</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Ковалев</surname><given-names>С. Г.</given-names></name><name name-style="western" xml:lang="en"><surname>Kovalev</surname><given-names>S. G.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Сергей Григорьевич Ковалев – доктор геол.-мин. наук, директор</p><p>450077, Уфа, ул. К. Маркса, д. 16/2</p></bio><bio xml:lang="en"><p>Sergey G. Kovalev – Director, DSc (Geology and Mineralogy)</p><p>16/2 Karl Marx st., Ufa, 450077</p></bio><email xlink:type="simple">kovalev@ufaras.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Ковалев</surname><given-names>С. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Kovalev</surname><given-names>S. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Сергей Сергеевич Ковалев – научный сотрудник</p><p>450077, Уфа, ул. К. Маркса, д. 16/2</p></bio><bio xml:lang="en"><p>Sergey S. Kovalev – Junior Researcher</p><p>16/2 Karl Marx st., Ufa, 450077</p></bio><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Институт геологии УФИЦ РАН</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Institute of Geology – Subdivision of the Ufa Federal Research Centre of the Russian Academy of Sciences</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2021</year></pub-date><pub-date pub-type="epub"><day>14</day><month>04</month><year>2024</year></pub-date><volume>23</volume><issue>4</issue><fpage>80</fpage><lpage>95</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Ковалев С.Г., Ковалев С.С., 2024</copyright-statement><copyright-year>2024</copyright-year><copyright-holder xml:lang="ru">Ковалев С.Г., Ковалев С.С.</copyright-holder><copyright-holder xml:lang="en">Kovalev S.G., Kovalev S.S.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.geors.ru/jour/article/view/167">https://www.geors.ru/jour/article/view/167</self-uri><abstract><p>В статье приводятся материалы по анализу химического состава силикатов и алюмосиликатов, слагающих дифференцированное тело мисаелгинского комплекса, которые позволили расчетными методами восстановить термобарические параметры кристаллизации расплава в промежуточной камере.Установлено наличие высокотемпературных (1472 ºС) интрателлурических кристаллов оливина, характеризующих процесс магмогенерации в мантии и оливина, кристаллизующегося в условиях промежуточной камеры (1050–1183 ºС). Рассчитанная температура кристаллизации пироксенов свидетельствует о том, что они кристаллизовались совместно с оливином основной массы пород, а установленные вариации Р–Т параметров (Т = 950–1045ºС, Р = 4.0–7.4 кбар) для плагиоклаза и амфибола завершают количественную характеристику высокотемпературных процессов кристаллизации расплава.Показано, что рассчитанные Р–Т параметры кристаллизации расплава, сформировавшего интрузивный массив, позволяют отнести его ультраосновной горизонт к пикритовым комплексам второго типа, выделенным нами ранее.Моделирование процесса кристаллизации осуществленное с использованием двух моделей – по алгоритму Х.Д. Натана и К.К. Ван-Кирка и программному продукту КОМАГМАТ, позволили установить, что наиболее вероятным механизмом формирования дифференцированного тела мисаелгинского комплекса являлась направленная кристаллизация с гравитационным осаждением оливина на начальных стадиях процесса становления массива.</p></abstract><trans-abstract xml:lang="en"><p>The article provides materials on the analysis of the chemical composition of silicates and aluminosilicates that make up the differentiated body of the Misaelga complex, which made it possible by calculation methods to restore the thermobaric parameters of crystallization of the melt in the intermediate chamberThe presence of high-temperature (1472 ºC) intratelluric olivine crystals characterizing the process of magma generation in the mantle and olivine crystallizing under the conditions of the intermediate chamber (1050–1183 ºC) has been established. The calculated crystallization temperature of pyroxenes indicates that they crystallized together with olivine from the bulk of the rocks, and the established variations in the P–T parameters (T = 950–1045 ºC, P = 4.0–7.4 kbar) for plagioclase and amphibole complete the quantitative characteristics of high-temperature melt crystallization processes.It is shown that the calculated Р–Т parameters of the crystallization of the melt that formed the intrusive massif make it possible to classify its ultrabasic horizon as picrite complexes of the second type that we identified earlier.Modeling of the crystallization process carried out using two models – according to the algorithm of H.D. Nathan and K.K. Van Kirk and the software product KOMAGMAT – made it possible to establish that the most probable mechanism for the formation of a differentiated body of the Misaelga complex was directional crystallization with gravitational deposition of olivine at the initial stages of the formation of the massif.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>Южный Урал</kwd><kwd>дифференцированное тело</kwd><kwd>оливин</kwd><kwd>клинопироксен</kwd><kwd>ортопироксен</kwd><kwd>моделирование</kwd><kwd>температура кристаллизации</kwd><kwd>дифференциация расплава</kwd><kwd>ликвидусные фазы</kwd></kwd-group><kwd-group xml:lang="en"><kwd>Southern Urals</kwd><kwd>differentiated body</kwd><kwd>olivine</kwd><kwd>clinopyroxene</kwd><kwd>orthopyroxene</kwd><kwd>modeling</kwd><kwd>crystallization temperature</kwd><kwd>melt differentiation</kwd><kwd>liquidus phases</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Исследования выполнены в рамках Государственного задания ИГ УФИЦ РАН (тема № 0252-2017-0012).</funding-statement><funding-statement xml:lang="en">The research was carried out within the framework of the State Assignment of the IG UFIC RAS (project No. 0252-2017-0012).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Алексеев А.А. (1984). Рифейксо-вендский магматизм западного склона Южного Урала. М.: Наука, 136 с.</mixed-citation><mixed-citation xml:lang="en">Aitcheson, S.J., Forrest, A.H. (1994). Quantification of crustal contamination in open magmatic systems. Journal of Petrology, 35, pр. 461–488. https://doi.org/10.1093/petrology/35.2.461</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Алексеев А.А., Алексеева Г.В., Ковалев С.Г. (2000). Расслоенные интрузии западного склона Урала. Уфа: Гилем, 188 с.</mixed-citation><mixed-citation xml:lang="en">Alekseev A.A. (1984). Riphean-Vendian magmatism of the western slope of the Southern Urals. Moscow: Nauka, 136 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Аппен А.А. (1974). Химия стекла. Л.: Химия, 125 с.</mixed-citation><mixed-citation xml:lang="en">Alekseev A.A., Alekseeva G.V., Kovalev S.G. (2000). Layered intrusions of the western slope of the Urals. Ufa: Gilem, 188 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Арискин А.А., Бармина Г.С. (2000). Моделирование фазовых равновесий при кристаллизации базальтовых магм. М.: Наука, 363 с.</mixed-citation><mixed-citation xml:lang="en">Appen A.A. (1974). Glass chemistry. Leningrad: Khimiya, 125 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Арискин А.А., Бармина Г.С., Френкель М.Ю. (1986). Имитация кристаллизации толеитовой магмы при низком давлении при фиксированной летучести кислорода. Geochem. Int., 24(5), с. 92–100.</mixed-citation><mixed-citation xml:lang="en">Ariskin A.A., Barmina G.S. (2004). COMAGMAT: Development of a magma crystallization model and its petrologic applications. Geochemistry International, 42(Suppl. 1), рp. 1–157.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Арискин А.А., Френкель М.Ю., Бармина Г.С., Нильсен Р. (1993). COMAGMAT: программа FORTRAN для моделирования процессов дифференциации магмы. Comput. Geosci., 19, с. 1155–1170. https://doi.org/10.1016/0098-3004(93)90020-6</mixed-citation><mixed-citation xml:lang="en">Ariskin A.A., Barmina G.S. (2000). Modelirovanie fazovykh ravnovesiy pri kristallizatsii bazal’tovykh magm. Moscow: Nauka, 363 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Бычков Д.А., Коптев-Дворников Е.В. (2005). Программа Кри-Минал для моделирования равновесия расплав–твердые фазы при заданном валовом составе системы. Матер. межд. конф.: Ультрамафитмафитовые комплексы складчатых областей докембрия. Улан-Удэ: Изд. БурНЦ СО РАН, с. 122–123.</mixed-citation><mixed-citation xml:lang="en">Ariskin A.A., Barmina G.S., Frenkel M.Yu. (1986). Computer simulation of basalt magma crystallization at a fixed oxygen fugacity. Geochem. Int., 24(5), pp. 92–100. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Дриц В.А., Коссовская А.Г. (1991). Глинистые минералы: слюды, хлориты. М: Наука, 176 с.</mixed-citation><mixed-citation xml:lang="en">Ariskin A.A., Frenkel M.Yu., Barmina G.S., Nilsen R. (1993). Comagmat: a Fortran program to model magma differentiation processes. Comput. Geosci., 19(8), pp. 1155–1170. https://doi.org/10.1016/0098-3004(93)90020-6</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Ерофеева К.Г., Степанова А.В., Самсонов А.В. Ларионова Ю.О., Егорова С.В., Арзамасцев А.А., Ковальчук Е.В. (2019). Базитовые дайки и силлы палеопротерозойского возраста (2400 млн лет) на севере Фенноскандии: петрология и коровая эволюция. Петрология, 27(1), с. 19–46.</mixed-citation><mixed-citation xml:lang="en">Beattie P. (1993). Olivine-melt and orthopyroxene-melt equilibria. Contributions to Mineralogy and Petrology, 115(1), рp. 103–111. https://doi.org/10.1007/BF00712982</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Ковалев С.Г. (1996). Дифференцированные диабаз-пикритовые комплексы западного склона Южного Урала. Уфа: ИГ УНЦ РАН, 99 с.</mixed-citation><mixed-citation xml:lang="en">Blundy J.D., Holland T.J.B. (1990). Calcic amphibole equilibria and a new amphibole-plagioclase geothermometer. Contrib Mineral Petrol, 104(2), pp. 208–224. https://doi.org/10.1007/BF00306444</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Ковалев С.Г. (2011). Новые данные по геохимии диабаз-пикритового магматизма западного склона Южного Урала и условия его формирования. Литосфера, 2, с. 68–83.</mixed-citation><mixed-citation xml:lang="en">Bohrson W.A., Spera F.J. (2001). Energy-Constrained Open-System Magmatic Processes II: Application of energy-constrained assimilation–fractional crystallization (EC-AFC) model to magmatic systems. J. Petrol., 42(5), рp. 1019–1041. https://doi.org/10.1093/petrology/42.5.1019</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Ковалев С.Г., Ковалев С.С., Высоцкий С.И. (2018). Благороднометалльная геохимическая специализация мезопротерозойских магматических комплексов Башкирского мегантиклинория и восточной окраины Восточно-Европейской платформы. Литосфера, 18(2), с. 295–313. https://doi.org/10.24930/1681-9004-2018-18-2-295-313</mixed-citation><mixed-citation xml:lang="en">Bohrson W.A., Spera F.J. (2003). Energy-constrained opensystem magmatic processes 4; Geochemical, thermal and mass consequences of Energy-Constrained Recharge, Assimilation and Fractional Crystallization (EC-RAFC). Geochem. Geophys. Geosyst., 4(2). https://doi.org/10.1029/2002GC000361</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Ковалев С.Г., Пучков В.Н., Высоцкий С.И., Ковалев С.С. (2017). Условия образования магматических пород при плюмовом процессе (на примере западного склона Южного Урала). ДАН, 475(2), с. 171–175. https://doi.org/10.7868/S0869565217200129</mixed-citation><mixed-citation xml:lang="en">Bowen N.L. (1928). The Evolution of the Igneous Rocks. Princeton University Press, Princeton, 334 p.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Ленных В.И., Петров В.И. (1978). Пикриты тараташского комплекса. Труды Ильмен. гос. заповед., вып. 17, с. 45–52.</mixed-citation><mixed-citation xml:lang="en">Bychkov D.A., Koptev-Dvornikov E.V. (2005). Cri-Minal program for modeling the melt-solid phase equilibrium for a given gross composition of the system. Proc. Conf.: Ultramafic-mafic complexes of folded areas of the Precambrian. Ulan-Ude: BurNTs SB RAS, pp. 122–123. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Мюллер Р., Саксена С. (1980). Химическая петрология. М.: Мир, 516 с.</mixed-citation><mixed-citation xml:lang="en">Campbell F.E., Roeder P. (1968). The stability of olivine and pyroxene in the Ni-Mg-Si-O system. Am. Mineralog, 53, pp. 257–268.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Носова А.А., Сазонова Л.В., Каргин А.В., Ларионова Ю.О., Горожанин В.М., Ковалев С.Г. (2012). Мезопротерозойская внутриплитная магматическая провинция Западного Урала: основные петрогенетические типы пород и их происхождение. Петрология, 20(4), с. 392–428.</mixed-citation><mixed-citation xml:lang="en">De Hoog Jan C.M., Gall Louise, David H.C. (2010). Trace-element geochemistry of mantle olivine and application to mantle petrogenesis and geothermobarometry. Chemical Geology, 270(1–4), pp. 196–215. https://doi.org/10.1016/j.chemgeo.2009.11.017</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Ползуненков Г.О. (2018). Оценка P-T и fO2 условий кристаллизации монцонитоидов Велиткенайского гранит-мигматитового массива (арктическая Чукотка) по данным минеральной термобаро- и оксибарометрии. Тихоокеанская геология, 37(5), с. 97–111.</mixed-citation><mixed-citation xml:lang="en">DePaolo D.J. (1981). Trace element and isotopic effects of combined wallrock assimilation and fractional crystallization. Earth and Planetary Science Letters, 53(2), рp. 189–202. https://doi.org/10.1016/0012-821X(81)90153-9</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Сазонова Л.В., Носова А.А., Ларионова Ю.О., Каргин А.В., Ковалев С.Г. (2011). Мезопротерозойские пикриты восточной окраины ВосточноЕвропейской платформы и Башкирского мегантиклинория: петрогенезис и особенности составов оливина и клинопироксена. Литосфера, 3, с. 64–83.</mixed-citation><mixed-citation xml:lang="en">Drits V.A., Kossovskaya A.G. (1991). Clay minerals: micas, chlorites. Moscow: Nauka, 176 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Уэйджер Л.П., Браун Г. (1970). Расслоенные изверженные породы. М., 552 с.</mixed-citation><mixed-citation xml:lang="en">Erofeeva, K.G., Stepanova, A.V., Samsonov, A.V. et al. (2019) 2.4 Ga Mafic Dikes and Sills of Northern Fennoscandia: Petrology and Crustal Evolution. Petrology, 27, pp. 17–42. https://doi.org/10.1134/S0869591119010016</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Френкель М.Я., Ярошевский А.А., Арискин А.А., и др. (1988). Динамика внутрикамерной дифференциации базитовых магм. М.: Наука, 216 с.</mixed-citation><mixed-citation xml:lang="en">Frenkel M.Ya., Yaroshevskiy A.A., Ariskin A.A., et al. (1988). Dynamics of intrachamber differentiation of basic magmas. Moscow: Nauka, 216 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Шарков Е.В. (1980). Петрология расслоенных интрузий. Л.: Наука,. 120 с.</mixed-citation><mixed-citation xml:lang="en">Fuchs L.H., Olsen E., Jensen K.J. (1973). Mineralogy, MineralChemistry, and Composition of the Murchison (C2) Meteorite. Smithson. Contrib. Earth Sci., 10, pp. 1–39. https://doi.org/10.5479/si.00810274.10.1</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Ярошевский А.А. (1964). Принцип зонной плавки и его применение при решении некоторых геохимических вопросов. Тр. геохимической конф.: Химия земной коры, т. 2. М.: Наука, с. 55–62.</mixed-citation><mixed-citation xml:lang="en">Gillis K.M., Snow J.E., Klaus A., Abe N., Adriao A.B., Akizawa N., Ceuleneer G., Cheadle M.J., Faak K., Falloon T.J., Friedman S.A., Godard M., Guerin G., Harigane Y., Horst A.J., Hoshide T., Ildefonse B., Jean M.M., John B.E., Koepke J., Machi S., Maeda J., Marks N.E., McCaig A.M., Meyer R., Morris A., Nozaka T., Python M., Saha A., Wintsch R.P. (2014) Primitive layered gabbros from fastspreading lower oceanic crust. Nature, 505, рp. 204–207. https://doi.org/10.1038/nature12778</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Aitcheson, S.J., Forrest, A.H. (1994). Quantification of crustal contamination in open magmatic systems. Journal of Petrology, 35, pр. 461–488. https://doi.org/10.1093/petrology/35.2.461</mixed-citation><mixed-citation xml:lang="en">Giret A., Bonin B., Leger J.M. (1980). Amphibole compositional trends in oversaturated alkaline plutonic ring-complexes. The Canadian Mineralogist, 18, pp. 481–495.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Ariskin A.A., Barmina G.S. (2004). COMAGMAT: Development of a magma crystallization model and its petrologic applications. Geochemistry International, 42(Suppl. 1), рp. 1–157.</mixed-citation><mixed-citation xml:lang="en">Humphreys M.C.S (2011) Silicate liquid immiscibility within the crystal mush: evidence from Ti in plagioclase from the Skaergaard intrusion. J Petrol., 52, рp. 147–174. https://doi.org/10.1093/petrology/egq076</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Beattie P. (1993). Olivine-melt and orthopyroxene-melt equilibria. Contributions to Mineralogy and Petrology, 115(1), рp. 103–111. https://doi.org/10.1007/BF00712982</mixed-citation><mixed-citation xml:lang="en">Kovalev S.G. (1996). Differentiated diabase-picrite complexes of the western slope of the Southern Urals. Ufa: IG UNTs RAS, 99 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Blundy J.D., Holland T.J.B. (1990). Calcic amphibole equilibria and a new amphibole-plagioclase geothermometer. Contrib Mineral Petrol, 104(2), pp. 208–224. https://doi.org/10.1007/BF00306444</mixed-citation><mixed-citation xml:lang="en">Kovalev S.G. (2011). New data on the geochemistry of diabase-picrite magmatism on the western slope of the Southern Urals and the conditions for its formation. Litosfera = Lithosphere (Russia), 2, pp. 68–83. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Bohrson W.A., Spera F.J. (2001). Energy-Constrained Open-System Magmatic Processes II: Application of energy-constrained assimilation–fractional crystallization (EC-AFC) model to magmatic systems. J. Petrol., 42(5), рp. 1019–1041. https://doi.org/10.1093/petrology/42.5.1019</mixed-citation><mixed-citation xml:lang="en">Kovalev S.G., Kovalev S.S., Vysotskiy S.I. (2018). Noble metal geochemical specialization of the Mesoproterozoic magmatic complexes of the Bashkirian meganticlinorium and the eastern margin of the East European platform. Litosfera = Lithosphere (Russia), 18(2), pp. 295–313. (In Russ.) https://doi.org/10.24930/1681-9004-2018-18-2-295-313</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Bohrson W.A., Spera F.J. (2003). Energy-constrained opensystem magmatic processes 4; Geochemical, thermal and mass consequences of Energy-Constrained Recharge, Assimilation and Fractional Crystallization (EC-RAFC). Geochem. Geophys. Geosyst., 4(2). https://doi.org/10.1029/2002GC000361</mixed-citation><mixed-citation xml:lang="en">Kovalev S.G., Puchkov V.N., Vysotskiy S.I., Kovalev S.S. (2017). Conditions for the formation of igneous rocks during the plume process (on the example of the western slope of the Southern Urals). DAN, 475(2), pp. 171–175. (In Russ.) https://doi.org/10.7868/S0869565217200129</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Bowen N.L. (1928). The Evolution of the Igneous Rocks. Princeton University Press, Princeton, 334 p.</mixed-citation><mixed-citation xml:lang="en">Kranidiotis P., MacLean W.H. (1987). Systematic of Chlorite Alteration at the Phelps Dodge Massive Sulfide Deposit, Matagami, Quebec. Economic Geology, 82(7), pp. 1808–1911. https://doi.org/10.2113/gsecongeo.82.7.1898</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Campbell F.E., Roeder P. (1968). The stability of olivine and pyroxene in the Ni-Mg-Si-O system. Am. Mineralog, 53, pp. 257–268.</mixed-citation><mixed-citation xml:lang="en">Kretz R. (1982). Transfer and exchange equilibria in a portion of the pyroxene quadrilateral as deduced from natural and experimental data. Geochimica et Cosmochimica Acta, 46(3), pp. 411–422. https://doi.org/10.1016/0016-7037(82)90232-0</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">De Hoog Jan C.M., Gall Louise, David H.C. (2010). Trace-element geochemistry of mantle olivine and application to mantle petrogenesis and geothermobarometry. Chemical Geology, 270(1–4), pp. 196–215. https://doi.org/10.1016/j.chemgeo.2009.11.017</mixed-citation><mixed-citation xml:lang="en">Layered Intrusions. (2015). Eds: Charlier B., Namur O., Latypov R., Tegner C. Springer, 748 p.</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">DePaolo D.J. (1981). Trace element and isotopic effects of combined wallrock assimilation and fractional crystallization. Earth and Planetary Science Letters, 53(2), рp. 189–202. https://doi.org/10.1016/0012-821X(81)90153-9</mixed-citation><mixed-citation xml:lang="en">Leak B.E. (1978). Nomenclature of amphiboles. Miner. Mag., 42(324), pp. 533–563. https://doi.org/10.1180/minmag.1978.042.324.21</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Fuchs L.H., Olsen E., Jensen K.J. (1973). Mineralogy, MineralChemistry, and Composition of the Murchison (C2) Meteorite. Smithson. Contrib. Earth Sci., 10, pp. 1–39. https://doi.org/10.5479/si.00810274.10.1</mixed-citation><mixed-citation xml:lang="en">Lennykh V.I., Petrov V.I. (1978). Picrites of the Taratash complex. Trudy Il’men. gos. zapoved., vol. 17, pp. 45–52. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">Gillis K.M., Snow J.E., Klaus A., Abe N., Adriao A.B., Akizawa N., Ceuleneer G., Cheadle M.J., Faak K., Falloon T.J., Friedman S.A., Godard M., Guerin G., Harigane Y., Horst A.J., Hoshide T., Ildefonse B., Jean M.M., John B.E., Koepke J., Machi S., Maeda J., Marks N.E., McCaig A.M., Meyer R., Morris A., Nozaka T., Python M., Saha A., Wintsch R.P. (2014) Primitive layered gabbros from fastspreading lower oceanic crust. Nature, 505, рp. 204–207. https://doi.org/10.1038/nature12778</mixed-citation><mixed-citation xml:lang="en">Lepage L.D. (2003). ILMAT: an excel worksheet for ilmenite-magnetite geothermometry and geobarometry. Comput. Geosci., 29(5), pp. 673–678. https://doi.org/10.1016/S0098-3004(03)00042-6</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Giret A., Bonin B., Leger J.M. (1980). Amphibole compositional trends in oversaturated alkaline plutonic ring-complexes. The Canadian Mineralogist, 18, pp. 481–495.</mixed-citation><mixed-citation xml:lang="en">Leuthold J, Blundy J.D, Holness M.B, Sides R. (2014) Successive episodes of reactive liquid flow through a layered intrusion (Unit 9, Rum Eastern Layered Intrusion, Scotland). Contrib. Mineral. Petrol., 168, рp. 1–27. https://doi.org/10.1007/s00410-014-1021-7</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Humphreys M.C.S (2011) Silicate liquid immiscibility within the crystal mush: evidence from Ti in plagioclase from the Skaergaard intrusion. J Petrol., 52, рp. 147–174. https://doi.org/10.1093/petrology/egq076</mixed-citation><mixed-citation xml:lang="en">Lindsley D.H., Spencer K.J. (1982). Fe-Ti oxide geothermometry: Reducing analyses of coexisting Ti-magnetite (Mt) and ilmenite (Ilm). American Geophysical Union, 63(18), p. 471.</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Kranidiotis P., MacLean W.H. (1987). Systematic of Chlorite Alteration at the Phelps Dodge Massive Sulfide Deposit, Matagami, Quebec. Economic Geology, 82(7), pp. 1808–1911. https://doi.org/10.2113/gsecongeo.82.7.1898</mixed-citation><mixed-citation xml:lang="en">Loucks Robert R. (1996). A precise olivine-augite Mg-Fe-exchange geothermometer. Contrib Mineral. Petrol., 125(2–3), рp. 140–150. https://doi.org/10.1007/s004100050211</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">Kretz R. (1982). Transfer and exchange equilibria in a portion of the pyroxene quadrilateral as deduced from natural and experimental data. Geochimica et Cosmochimica Acta, 46(3), pp. 411–422. https://doi.org/10.1016/0016-7037(82)90232-0</mixed-citation><mixed-citation xml:lang="en">Miyamoto M., Furuta T., Fujii NMcKay., D.S., Lofgren G.E., Duke M.B. (1993). The Mn-Fe negative correlation in olivines in ALHA 77257 ureilite. Journal of Geophysical Research, 98(E3), pp. 5301–5307. https://doi.org/10.1029/92JE02943</mixed-citation></citation-alternatives></ref><ref id="cit39"><label>39</label><citation-alternatives><mixed-citation xml:lang="ru">Layered Intrusions. (2015). Eds: Charlier B., Namur O., Latypov R., Tegner C. Springer, 748 p.</mixed-citation><mixed-citation xml:lang="en">Myuller R., Saksena S. (1980). Chemical petrology. Moscow: Mir, 516 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit40"><label>40</label><citation-alternatives><mixed-citation xml:lang="ru">Leak B.E. (1978). Nomenclature of amphiboles. Miner. Mag., 42(324), pp. 533–563. https://doi.org/10.1180/minmag.1978.042.324.21</mixed-citation><mixed-citation xml:lang="en">Namur O, Charlier B, Toplis M.J, Higgins M.D, Liégeois J-P, Vander Auwera J. (2010) Crystallization sequence and magma chamber processes in the ferrobasaltic Sept Iles layered intrusion, Canada. J. Petrol., 51, pp. 1203–1236. https://doi.org/10.1093/petrology/egq016</mixed-citation></citation-alternatives></ref><ref id="cit41"><label>41</label><citation-alternatives><mixed-citation xml:lang="ru">Lepage L.D. (2003). ILMAT: an excel worksheet for ilmenite-magnetite geothermometry and geobarometry. Comput. Geosci., 29(5), pp. 673–678. https://doi.org/10.1016/S0098-3004(03)00042-6</mixed-citation><mixed-citation xml:lang="en">Nathan H.D., Vankirk C.K. (1978). A model of magmatic crystallization. Petrol., 19(1), pp. 66–94. https://doi.org/10.1093/petrology/19.1.66</mixed-citation></citation-alternatives></ref><ref id="cit42"><label>42</label><citation-alternatives><mixed-citation xml:lang="ru">Leuthold J, Blundy J.D, Holness M.B, Sides R. (2014) Successive episodes of reactive liquid flow through a layered intrusion (Unit 9, Rum Eastern Layered Intrusion, Scotland). Contrib. Mineral. Petrol., 168, рp. 1–27. https://doi.org/10.1007/s00410-014-1021-7</mixed-citation><mixed-citation xml:lang="en">Nielsen R.L. (1985). EQUIL: a program for the modeling of low-pressure differentiation processes in natural mafic magma bodies. Computers &amp; Geosciences, 11, рp. 531–546. https://doi.org/10.1016/0098-3004(85)90084-6</mixed-citation></citation-alternatives></ref><ref id="cit43"><label>43</label><citation-alternatives><mixed-citation xml:lang="ru">Lindsley D.H., Spencer K.J. (1982). Fe-Ti oxide geothermometry: Reducing analyses of coexisting Ti-magnetite (Mt) and ilmenite (Ilm). American Geophysical Union, 63(18), p. 471.</mixed-citation><mixed-citation xml:lang="en">Nielsen R.L. (1988). TRACE FOR: A program for the calculation of combined major and trace-element liquid lines of descent for natural magmatic systems. Computers &amp; Geosciences, 14, рp. 15–35. https://doi.org/10.1016/0098-3004(88)90050-7</mixed-citation></citation-alternatives></ref><ref id="cit44"><label>44</label><citation-alternatives><mixed-citation xml:lang="ru">Loucks Robert R. (1996). A precise olivine-augite Mg-Fe-exchange geothermometer. Contrib Mineral. Petrol., 125(2–3), рp. 140–150. https://doi.org/10.1007/s004100050211</mixed-citation><mixed-citation xml:lang="en">Nosova, A.A., Sazonova, L.V., Kargin, A.V. et al. (2012) Mesoproterozoic within-plate igneous province of the western urals: Main petrogenetic rock types and their origin. Petrology, 20, pp. 356–390. https://doi.org/10.1134/S086959111204008X</mixed-citation></citation-alternatives></ref><ref id="cit45"><label>45</label><citation-alternatives><mixed-citation xml:lang="ru">Miyamoto M., Furuta T., Fujii NMcKay., D.S., Lofgren G.E., Duke M.B. (1993). The Mn-Fe negative correlation in olivines in ALHA 77257 ureilite. Journal of Geophysical Research, 98(E3), pp. 5301–5307. https://doi.org/10.1029/92JE02943</mixed-citation><mixed-citation xml:lang="en">Perchuk L.L., Saxena S.K and Bhattacharji S. (1977). Thermodynamic control of metamorphic processes in Energetics of Geological Processes. New York: Springer.https://doi.org/10.1007/978-3-642-86574-9</mixed-citation></citation-alternatives></ref><ref id="cit46"><label>46</label><citation-alternatives><mixed-citation xml:lang="ru">Namur O, Charlier B, Toplis M.J, Higgins M.D, Liégeois J-P, Vander Auwera J. (2010) Crystallization sequence and magma chamber processes in the ferrobasaltic Sept Iles layered intrusion, Canada. J. Petrol., 51, pp. 1203–1236. https://doi.org/10.1093/petrology/egq016</mixed-citation><mixed-citation xml:lang="en">Polzunenkov G.O. (2018). Evaluation of P-T and fO2 conditions of crystallization of monzonitoids of the Velitkenai granite-migmatite massif (Arctic Chukotka) based on mineral thermobaro- and oxybarometry data. Tikhookeanskaya geologiya, 37(5), pp. 97–111. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit47"><label>47</label><citation-alternatives><mixed-citation xml:lang="ru">Nathan H.D., Vankirk C.K. (1978). A model of magmatic crystallization. Petrol., 19(1), pp. 66–94. https://doi.org/10.1093/petrology/19.1.66</mixed-citation><mixed-citation xml:lang="en">Powell R. (1984). Inversion of the assimilation and fractional crystallization (AFC) equations; characterization of contaminants from isotope and trace element relationships in volcanic suites. Journal of Geological Society of London, 141(3), рp. 447–452. https://doi.org/10.1144/gsjgs.141.3.0447</mixed-citation></citation-alternatives></ref><ref id="cit48"><label>48</label><citation-alternatives><mixed-citation xml:lang="ru">Nielsen R.L. (1985). EQUIL: a program for the modeling of low-pressure differentiation processes in natural mafic magma bodies. Computers &amp; Geosciences, 11, рp. 531–546. https://doi.org/10.1016/0098-3004(85)90084-6</mixed-citation><mixed-citation xml:lang="en">Roedder P.L., Emslie R.F. (1970). Olivine-liquid equilibrium. Contributions to Mineralogy and Petrology, 29(4), рp. 275–289. https://doi.org/10.1007/BF00371276</mixed-citation></citation-alternatives></ref><ref id="cit49"><label>49</label><citation-alternatives><mixed-citation xml:lang="ru">Nielsen R.L. (1988). TRACE FOR: A program for the calculation of combined major and trace-element liquid lines of descent for natural magmatic systems. Computers &amp; Geosciences, 14, рp. 15–35. https://doi.org/10.1016/0098-3004(88)90050-7</mixed-citation><mixed-citation xml:lang="en">Sazonova L.V., Nosova A.A., Larionova Yu.O., Kargin A.V., Kovalev S.G. (2011). Mesoproterozoic picrites of the eastern margin of the East European Platform and the Bashkirian meganticlinorium: petrogenesis and compositional features of olivine and clinopyroxene. Litosfera = Lithosphere (Russia), 3, pp. 64–83. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit50"><label>50</label><citation-alternatives><mixed-citation xml:lang="ru">Perchuk L.L., Saxena S.K and Bhattacharji S. (1977). Thermodynamic control of metamorphic processes in Energetics of Geological Processes. New York: Springer.https://doi.org/10.1007/978-3-642-86574-9</mixed-citation><mixed-citation xml:lang="en">Sharkov E.V. (1980). Petrology of layered intrusions. Leningrad: Nauka, 120 p. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit51"><label>51</label><citation-alternatives><mixed-citation xml:lang="ru">Powell R. (1984). Inversion of the assimilation and fractional crystallization (AFC) equations; characterization of contaminants from isotope and trace element relationships in volcanic suites. Journal of Geological Society of London, 141(3), рp. 447–452. https://doi.org/10.1144/gsjgs.141.3.0447</mixed-citation><mixed-citation xml:lang="en">Spera F.J., Bohrson W.A. (2001). Energy-constrained opensystem magmatic processes, 1, General model and energyconstrained assimilation and fractional crystallization (ECAFC) formulation. J. Petrol., 42(5), рp. 999–1018. https://doi.org/10.1093/petrology/42.5.999</mixed-citation></citation-alternatives></ref><ref id="cit52"><label>52</label><citation-alternatives><mixed-citation xml:lang="ru">Roedder P.L., Emslie R.F. (1970). Olivine-liquid equilibrium. Contributions to Mineralogy and Petrology, 29(4), рp. 275–289. https://doi.org/10.1007/BF00371276</mixed-citation><mixed-citation xml:lang="en">Spera F.J., Bohrson W.A. (2002). Energy-constrained opensystem magmatic processes 3. Energy-constrained recharge, assimilation, and fractional crystallization (EC-RAFC). Geochemistry Geophysics Geosystems, 3(12), рp. 1–20. https://doi.org/10.1029/2002GC000315</mixed-citation></citation-alternatives></ref><ref id="cit53"><label>53</label><citation-alternatives><mixed-citation xml:lang="ru">Spera F.J., Bohrson W.A. (2001). Energy-constrained opensystem magmatic processes, 1, General model and energyconstrained assimilation and fractional crystallization (ECAFC) formulation. J. Petrol., 42(5), рp. 999–1018. https://doi.org/10.1093/petrology/42.5.999</mixed-citation><mixed-citation xml:lang="en">Spera F.J., Bohrson W.A. (2004). Open-system magma chamber evolution: an energy-constrained geochemical model incorporating the effects of concurrent eruption, recharge, variable assimilation and fractional crystallization (EC-E’RA FC). Journal of Petrology, 45(12), рp. 2459–2480. https://doi.org/10.1093/petrology/egh072</mixed-citation></citation-alternatives></ref><ref id="cit54"><label>54</label><citation-alternatives><mixed-citation xml:lang="ru">Spera F.J., Bohrson W.A. (2002). Energy-constrained opensystem magmatic processes 3. Energy-constrained recharge, assimilation, and fractional crystallization (EC-RAFC). Geochemistry Geophysics Geosystems, 3(12), рp. 1–20. https://doi.org/10.1029/2002GC000315</mixed-citation><mixed-citation xml:lang="en">Toramaru A, Matsumoto M. (2012) Numerical experiment of cyclic layering in a solidified binary eutectic melt. J. Geophys. Res., 117, B02209. https://doi.org/10.1029/2011JB008204</mixed-citation></citation-alternatives></ref><ref id="cit55"><label>55</label><citation-alternatives><mixed-citation xml:lang="ru">Spera F.J., Bohrson W.A. (2004). Open-system magma chamber evolution: an energy-constrained geochemical model incorporating the effects of concurrent eruption, recharge, variable assimilation and fractional crystallization (EC-E’RA FC). Journal of Petrology, 45(12), рp. 2459–2480. https://doi.org/10.1093/petrology/egh072</mixed-citation><mixed-citation xml:lang="en">Wager L.P., Brown G. (1968). Layered igneous rocks. Edinburgh; London: Oliver &amp; Boyd, 588 p.</mixed-citation></citation-alternatives></ref><ref id="cit56"><label>56</label><citation-alternatives><mixed-citation xml:lang="ru">Toramaru A, Matsumoto M. (2012) Numerical experiment of cyclic layering in a solidified binary eutectic melt. J. Geophys. Res., 117, B02209. https://doi.org/10.1029/2011JB008204</mixed-citation><mixed-citation xml:lang="en">Wells P.R.A. (1977). Pyroxene thermometry in simple and complex systems. Contributions to Mineralogy and Petrology, 62(2), pp. 129–139. https://doi.org/10.1007/BF00372872</mixed-citation></citation-alternatives></ref><ref id="cit57"><label>57</label><citation-alternatives><mixed-citation xml:lang="ru">Wells P.R.A. (1977). Pyroxene thermometry in simple and complex systems. Contributions to Mineralogy and Petrology, 62(2), pp. 129–139. https://doi.org/10.1007/BF00372872</mixed-citation><mixed-citation xml:lang="en">Wood B.J., Banno S. (1973). Garnet-orthopyroxene and orthopyroxeneclinopyroxene relationships in simple and complex systems. Contributions to Mineralogy and Petrology, 42(2), pp. 109–124. https://doi.org/10.1007/BF00371501</mixed-citation></citation-alternatives></ref><ref id="cit58"><label>58</label><citation-alternatives><mixed-citation xml:lang="ru">Wood B.J., Banno S. (1973). Garnet-orthopyroxene and orthopyroxeneclinopyroxene relationships in simple and complex systems. Contributions to Mineralogy and Petrology, 42(2), pp. 109–124. https://doi.org/10.1007/BF00371501</mixed-citation><mixed-citation xml:lang="en">Yaroshevskiy A.A. (1964). The principle of zone melting and its application in solving some geochemical issues. Proc. Conf.: Chemistry of the Earth’s Crust, vol. 2. Moscow: Nauka, pp. 55–62. (In Russ.)</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
