georesГеоресурсыGeoresources1608-50431608-5078Georesursy LLC10.18599/grs.2023.4.16geores-22Research ArticleСТАТЬИRESEARCH ARTICLESЭволюция состава стабильных изотопов водорода, кислорода и углерода в водах нефтегазоносных отложений северных районов Западной СибириEvolution of the composition of Н, О and C stable isotopes in the groundwaters of oil and gas bearing sediments in the northern regions of West SiberiaНовиковД. А.NovikovD. A.

Дмитрий Анатольевич Новиков – кандидат геол.- минерал. наук, заведующий лабораторией;

доцент

630090, Новосибирск, пр. Академика Коптюга, д. 3.

DmitryA.Novikov – Cand. Sci. (Geology and Mineralogy), Head of the Laboratory;

Associate Professor

3 Ak.Koptyug ave., Novosibirsk, 630090

NovikovDA@ipgg.sbras.ruПыряевА. Н.PyrayevA. N.

Александр Николаевич Пыряев – кандидат хим. наук, научный сотрудник;

старший преподаватель кафедры химической и биологической физики

630090, Новосибирск, пр. Академика Коптюга, д. 3

Aleksandr N. Pyrayev – Cand. Sci. (Chemistry), Researcher;

Senior Lecturer

3 Ak.Koptyug ave., Novosibirsk, 630090

МаксимоваА. А.MaximovaA. A.

Анастасия Алексеевна Максимова – младший научный сотрудник;

ассистент кафедры минералогии и геохимии

630090, Новосибирск, пр. Академика Коптюга, д. 3

Anastasia A. Maksimova – Junior Researcher;

Assistant of the Department

3 Ak.Koptyug ave., Novosibirsk, 630090

ДульцевФ. Ф.DultsevF. F.

Федор Федорович Дульцев – научный сотрудник

630090, Новосибирск, пр. Академика Коптюга, д. 3

Fedor F. Dultsev – Researcher

3 Ak.Koptyug ave., Novosibirsk, 630090

ЧерныхА. В.ChernykhA. V.

Анатолий Витальевич Черных – научный сотрудник

630090, Новосибирск, пр. Академика Коптюга, д. 3

Anatoly V. Chernykh – Researcher

3 Ak.Koptyug ave., Novosibirsk, 630090

Институт нефтегазовой геологии и геофизики им. А.А. Трофимука СО РАН; Новосибирский государственный университетРоссияTrofimuk Institute of Petroleum Geology and Geophysics of the Siberian Branch of the Russian Academy of Sciences; Novosibirsk State UniversityRussian FederationИнститут геологии и минералогии им. В.С. Соболева СО РАН; Новосибирский государственный университетРоссияV.S. Sobolev Institute of Geology and Mineralogy of the Siberian Branch of the Russian Academy of Sciences; Novosibirsk State UniversityRussian FederationИнститут нефтегазовой геологии и геофизики им. А.А. Трофимука СО РАНРоссияTrofimuk Institute of Petroleum Geology and Geophysics of the Siberian Branch of the Russian Academy of SciencesRussian Federation202331032024254219232Copyright © Новиков Д.А., Пыряев А.Н., Максимова А.А., Дульцев Ф.Ф., Черных А.В., 20242024Новиков Д.А., Пыряев А.Н., Максимова А.А., Дульцев Ф.Ф., Черных А.В.Novikov D.A., Pyrayev A.N., Maximova A.A., Dultsev F.F., Chernykh A.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.geors.ru/jour/article/view/22

В работе представлены результаты исследования изотопного состава кислорода и водорода вод и углерода водорастворенной углекислоты для нефтегазоносных отложений северных районов Западной Сибири, охватывающих широкий стратиграфический диапазон – мезозой (от сеномана до байоса) и частично палеозой. Полученные значения δD и δ18O – очень разнообразны, охватывают интервалы от –120‰ до –50‰ и от –17‰ до –2‰ соответственно. Такой разнообразный изотопный состав вод указывает на отсутствие унифицированного механизма накопления вод и их преобразование в ходе геологической эволюции Западно-Сибирского осадочного бассейна. Главной чертой большинства изученных вод является выраженные значения изотопных кислородных сдвигов относительно GMWL (Global meteoric water line), в целом нарастающие с увеличением возраста водовмещающих отложений и достигающие 9‰, что указывает на их древнее седиментационное происхождение.Диапазоны вариации изотопного состава углерода растворенной в воде углекислоты (от –51,8‰ до +21,8‰) и его содержания в водах (от 0,2 до 38,6 ммоль/дм3 ) указывают на широкий спектр условий и процессов, участвующих в преобразовании водорастворенной углекислоты. Тем не менее, установлена общая закономерность изменения изотопного состава углерода CO2 во времени. На основании полученных данных предложена модель преобразования изотопного состава углерода углекислоты в виде замкнутого цикла «атмосфера – почвы – глубокие водоносные горизонты», основанная на данных по изотопному составу водорастворенной углекислоты в водах нефтегазоносных отложений северных районов Западной Сибири.

The results of a study of the isotopic composition of oxygen and hydrogen of groundwater and dissolved inorganic carbon in oil and gas deposits of the northern regions of Western Siberia, covering a wide stratigraphic range – Mesozoic and Paleozoic are presented. The obtained values are very diverse, covering the intervals from –120 to –50‰ (δD) and from –17 to –2‰ (δ18O). Such a variable isotopic composition of waters indicates the absence of a unified mechanism for the accumulation of waters and their transformation during the geological evolution of the West Siberian sedimentary basin. The main feature of most of the studied waters is the pronounced values of oxygen isotope shifts relative to GMWL, which generally increase with the age of water-bearing deposits and reach 9‰, which indicates their ancient sedimentary origin.Variations in the isotopic composition of DIC (from –51.8 to +21.8‰) and its content in waters (from 0.2 to 38.6 mmol/I) indicate a wide range of water burial conditions and processes involved in the conversion of water-soluble carbon dioxide. A general pattern of changes in the isotopic composition of carbon in CO2 with time, expressed in general form by damped oscillations of the “isotope oscillator”, is revealed. A model of transformation of the carbon isotope composition in carbon dioxide in the closed cycle “atmosphere-soils-deep aquifers” for oil and gas deposits of the northern regions of Western Siberia based on the obtained isotope data is proposed.

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The authors declare that there are no conflicts of interest present.