georesГеоресурсыGeoresources1608-50431608-5078Georesursy LLC10.18599/grs.2024.4.2geores-410Research ArticleГЕОЛОГО-ГЕОХИМИЧЕСКИЕ ИССЛЕДОВАНИЯ, ПОИСК И РАЗВЕДКА МЕСТОРОЖДЕНИЙ ПОЛЕЗНЫХ ИСКОПАЕМЫХGEOLOGICAL AND GEOCHEMICAL RESEARCH, PROSPECTING AND EXPLORATION OF DEPOSITSИсследование кинетики термического преобразования органического вещества нефтегазоматеринских пород: обзор методов и экспериментальные результатыKinetics of Organic Matter thermal transformation in source rocks: Overview of Methods and Experimental resultsСпасенныхМ. Ю.SpasennykhM.

Михаил Юрьевич Спасенных – кандидат хим. наук, профессор, директор Центра науки и технологий добычи углеводородов.

121205, Москва, Большой бульвар, д. 30, стр.1

Mikhail Spasennykh – Professor, Director of the Center for Petroleum Science and Engineering.

Buil. 1, 30, Bolshoy Boulevard, Moscow, 121205

m.spasennykh@skoltech.ruШироковаВ. В.ShirokovaV.

Вероника Вадимовна Широков а – аспирант.

121205, Москва, Большой бульвар, д. 30, стр.1

Veronika Shirokova – PhD student.

Buil. 1, 30, Bolshoy Boulevard, Moscow, 121205

veronika.shirokova@skoltech.ruИльменскийА. С.IlmenskiiA.

Алексей Сергеевич Ильменский – аспирант.

121205, Москва, Большой бульвар, д. 30, стр.1

Aleksei Ilmenskii – PhD student.

Buil. 1, 30, Bolshoy Boulevard, Moscow, 121205

aleksei.ilmenskii@skoltech.ruКозловаЕ. В.KozlovaE.

Елена Владимировна Козлова – кандидат геол.-минерал. наук, ведущий научный сотрудник.

121205, Москва, Большой бульвар, д. 30, стр.1

Elena Kozlova – PhD in Geology, leading research scientist.

Buil. 1, 30, Bolshoy Boulevard, Moscow, 121205

e.kozlova@skoltech.ruБулатовТ. Д.BulatovT.

Тимур Дамирович Булатов – PhD, научный сотрудник.

121205, Москва, Большой бульвар, д. 30, стр.1

Timur Bulatov – PhD in Petroleum Engineering, research scientist.

Buil. 1, 30, Bolshoy Boulevard, Moscow, 121205

timur.bulatov@skoltech.ruГончароваА. В.GoncharovaA.

Арина Владимировна Гончарова – инженер.

121205, Москва, Большой бульвар, д. 30, стр.1

Arina Goncharova – engineer.

Buil. 1, 30, Bolshoy Boulevard, Moscow, 121205

a.goncharova@skoltech.ruЛеушинаЕ. А.LeushinaE.

Евгения Андреевна Леушина – кандидат хим. наук, ведущий научный сотрудник.

121205, Москва, Большой бульвар, д. 30, стр.1

Evgenia Leushina – PhD in Chemistry, leading research scientist.

Buil. 1, 30, Bolshoy Boulevard, Moscow, 121205

e.leushina@skoltech.ruСколковский институт науки и технологийРоссияSkolkovo Institute of Science and TechnologyRussian Federation202430122024264319Copyright © Спасенных М.Ю., Широкова В.В., Ильменский А.С., Козлова Е.В., Булатов Т.Д., Гончарова А.В., Леушина Е.А., 20242024Спасенных М.Ю., Широкова В.В., Ильменский А.С., Козлова Е.В., Булатов Т.Д., Гончарова А.В., Леушина Е.А.Spasennykh M., Shirokova V., Ilmenskii A., Kozlova E., Bulatov T., Goncharova A., Leushina E.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.geors.ru/jour/article/view/410

Исследования кинетики термического преобразования органического вещества нефтегазоматеринских пород являются частью геохимических исследований нефтяных систем, результаты которых используются при оценке объема генерации углеводородов в нефтегазоносных бассейнах с помощью методов бассейнового моделирования. Кинетические данные также необходимы для оптимизации параметров технологий внутрипластовой генерации углеводородов (температуры, времени воздействия) при применении тепловых методов увеличения нефтеотдачи.

В работе обобщены современные представления о кинетике термического преобразования органического вещества нефтегазоматеринских пород, дан обзор аппаратуры и экспериментальных методов получения однокомпонентных и композиционных спектров энергий активации в открытой и закрытой системах, описаны преимущества, недостатки и области применения различных подходов.

Детально описаны экспериментальные методики определения кинетических спектров с помощью комплекса аналитических методов, включающего пиролиз Rock-Eval и пиролитическую хроматомасс-спектрометрию (открытая система), а также оборудования на основе мини-автоклавов (закрытая система). Приведены примеры кинетических спектров, полученных для нефтегазоматеринских пород РФ включая: (i) однокомпонентные кинетические спектры, позволяющие прогнозировать суммарный выход мобильных углеводородов при преобразовании керогена; (ii) композиционные кинетические спектры с разделением состава продуктов крекинга органического вещества; (iii) кинетические модели преобразования органического вещества, включающие реакции вторичного крекинга углеводородов в закрытой системе.

The paper is devoted to kinetic studies of thermal decomposition of organic matter in organic-rich rocks. Kinetic studies are the consisting part of geochemical investigations of source rocks and petroleum systems. The results are required for petroleum generation prediction and assessment of reservoir hydrocarbons quantity and quality using basin modelling. Kinetic data is also applied for simulation of in-situ kerogen conversion and hydrocarbons generation, which are the main processes of thermal methods of enhanced oil recovery (thermal EOR).

The paper summarizes fundamental concepts and experimental approaches for kinetic studies of organic matter thermal transformation, it provides an overview of modern methods, equipment and experimental procedures for obtaining bulk and compositional activation energy distributions (spectra) in open and closed systems, and discusses the benefits, limitations, and possible applications of the different methods.

The paper presents the scope of experimental procedures, which have been elaborated at Skoltech, and the obtained results: (i) bulk kinetic spectra, which are aimed at express prediction of the total yield of mobile hydrocarbons during kerogen transformation; (ii) compositional kinetic spectra, which considers the amount and composition of hydrocarbon products; (iii) kinetic model of organic matter transformation in a closed system, which considers primary kerogen decomposition and secondary reactions of the hydrocarbons. The kinetic spectra were obtained for various organic-rich rocks collected within the Russian Federation.

расчет кинетических спектровкерогеннефтегазоматеринские породыпиролизгенерация нефти и газакомпозиционная кинетикакинетика в закрытой системеcalculation of Ea distributionkerogensource rockpyrolysispetroleum generationcompositional kineticsclosed-system kineticsработа поддержана Министерством науки и высшего образования российской Федерации по соглашению № 075-10-2022-011 от 20.04.2022 в рамках программы развития НЦМУThe work was supported by the Ministry of Science and Higher Education of the Russian Federation under agreement No. 075-10-2022-011 from 20.04.2022 within the framework of the NCMU development programReferencesАстахов С.М. (2016). Кинетические спектры реакций преобразования органического вещества нефтегазоматеринских отложений. Нефтегазовая геология. Теория и практика, 11(1), pp. 1–28. https://doi.org/10.17353/2070-5379/5_2016Aizenshtat Z., Miloslavsky I., Heller-Kallai L. (1984). 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The authors declare that there are no conflicts of interest present.