Preview

Georesources

Advanced search

Carbonate reservoir rocks characterization of the Kazanian Stage of the Gorsky ultraviscous oil field by electron paramagnetic resonance method

https://doi.org/10.18599/grs.2022.3.8

Abstract

The use of the electron paramagnetic resonance (EPR) method for studying carbonate rocks is widespread. EPR makes it possible to reconstruct lithological and geochemical environments of ancient sedimentation, including redox conditions and paleo-radioactivity of sedimentation basins. The paper considers the heterogeneous structure of carbonate reservoir rocks of the Kazanian Stage of the Gorsky ultraviscous oil field by paramagnetic marks: manganese ions Mn2+, radical ions SO3 , SO2 , РO2 2-(РO2 0 ) in carbonate minerals and radical С600 in the remains of organic matter in the rock. The carbonate reservoirs of the Gorsky structure, tectonically confined to the eastern side of the Melekess Depression, are represented by two main lithotypes: dolomitic boundstones and dolomitic oolitic packstones, which have various post-sedimentary alterations. EPR data were obtained for 28 samples with a step of 0.5- 1.5 m along the section. The EPR spectra are characterized by narrow lines that indicate the marine origin of carbonates. Based on the EPR spectra of the ions Mn2+ and its content in carbonate minerals, the lagoonal-marine genesis of the Gorsky structure rocks was revealed. The dominant dolomite mineralization of the section was established. The absence of dolomite radicals and low values of the degree of population of the magnesium and calcium positions of dolomites are due to the secondary nature of carbonates. The distribution of manganese ions, organic and inorganic radicals in the rock along the section is shown simultaneously with its reservoir properties and the conditions for the formation of two dolomite lithotypes.

About the Authors

R. A. Mudarisova
Kazan (Volga Region) Federal University
Russian Federation

Raushania A. Mudarisova – Senior Lecturer, Trofimuk Department of Oil and Gas Geology

4/5, Kremlin st., Kazan, 420111



Yu. V. Volkov
Kazan (Volga Region) Federal University; Institute of Ecology and Subsoil Use of Tatarstan Academy of Sciences
Russian Federation

Yuri V. Volkov – Cand. Sci. (Geology and Mineralogy), 1) Associate Professor, Trofimuk Department of Oil and Gas Geology;

Senior Researcher, Laboratory of Geological and Ecological Modeling

4/5, Kremlin st., Kazan, 420111



N. M. Khasanova
Kazan (Volga Region) Federal University
Russian Federation

Nailya M. Khasanova – Cand. Sci. (Physics and Mathematics), Researcher, Research Laboratory of Stratigraphy of Oil and Gas Reservoirs

4/5, Kremlin st., Kazan, 420111



B. V. Uspensky
Kazan (Volga Region) Federal University; Institute of Ecology and Subsoil Use of Tatarstan Academy of Sciences
Russian Federation

Boris V. Uspensky – Dr. Sci. (Geology and Mineralogy),

Head of the Trofimuk Department of Oil and Gas Geology;

Senior Researcher, Laboratory of Geological and Ecological Modeling

4/5, Kremlin st., Kazan, 420111



References

1. Bulka G.R., Nizamutdinov N.M., Mukhutdinova N.G., Vinokurov V.M., Galeev A.A. (1991). EPR probes in sedimentary rocks: the features of Mn2+ and free radicals distribution in the Permian formation in Tatarstan. Appl. Magn. Reson., 2(1), pp. 107-115.

2. Etkinsk P.U., Saimons M. (1970). EPR Spectra and the Structure of Inorganic Radicals. Trans. from Eng. E.D. German; Ed. M.E. Dyatkin. Moscow: Mir, 310 p. (In Russ.)

3. Fakhrutdinov E.I., Nurgalieva N.G., Khasanova N.M., Silant’ev V.V. (2015). Lithological and facies features of the Lower Kazan deposits according to the EPR data of the reference section. Uchenye Zapiski Kazanskogo Universiteta. Seriya Estestvennye Nauki, 157(3), pp. 87–101. (In Russ.)

4. Gatiyatullin N.S. (2010). A feature of the spatial distribution of Permian bitumen and underlying oil deposits on the territory of the Republic of Tatarstan. Neftegazovaya geologiya. Teoriya i praktika, 5(3), pp. 1-9. (In Russ.)

5. Herndon E.M., Havig J.R., Singer D.M., McCormick M.L., Kump L.R. (2018). Manganese and iron geochemistry in sediments underlying the redoxstratified Fayetteville Green Lake. Geochimica et Cosmochimica Acta, 231, pp. 50-63. DOI: 10.1016/j.gca.2018.04.013

6. Ignat’ev V.I. (1976). Formation of the Volga-Ural anticlise in the Permian period. Kazan: Kazan State University, 256 p. (In Russ.)

7. Khasanov R.R. (1999). Geochemical evolution of the Late Permian sedimentary basin of the Volga-Kama region Upper Permian stratotypes of the Volga region. Proc. Int. Symp. Moscow: GEOS, pp. 151-156. (In Russ.)

8. Krotov B.P. (1925). Dolomites, their formation, conditions of stability in the earth’s crust and changes in connection with the study of dolomites of the upper horizons of the Kazan stage in the vicinity of Kazan. Trudy Kazanskogo obshchestva estestvoispytatelei, 50(6). (In Russ.)

9. Krutikov V.F. (2001). Radiospectroscopy of minerals and rocks of nonmetallic mineral deposits. Dr. geol.-min. sci. diss. Kazan, 287 p. (In Russ.)

10. Lloyd R.V., Morie C.S., Lumsden D.N. (1991). ESR-determined manganese partitioning ratios in dolomite synthesized at 180° and 250°C. Chemical Geology, 105, pp. 253-257. DOI: 10.1016/0009-2541(93)90129-7

11. Maidl’ T.V., Lyutoev V.P., Dan’shchikova I.I., Golovataya O.S. (2017). The use of electron paramagnetic resonance to reveal signs of tectonic transformations in carbonate rocks of thrust zones (on the example of the Silurian-Ordovician deposits of the 1-Adakskaya well, the central part of the Chernyshev Ridge). Vestnik IG Komi ITs UrO RAN, 2, pp. 29-40. (In Russ.)

12. DOI: 10.19110/2221-1381-2017-2-29-40 Mudarisova R.A., Uspenskii B.V., Volkov Yu.V., Khasanova N.M., Baranova A.G. (2020). Lithological-facies features of the Lower Kazan deposits according to EPR data on the example of the Gorskoye deposit. Ekspozitsiya. Neft’.Gaz, 4(77), pp. 15-19. (In Russ.) DOI:10.24411/2076-6785-2020-10115

13. Murav’ev F.A. (2007). Lithological and mineralogical characteristics of the Permian marker carbonate horizons of the Republic of Tatarstan. Cand. geol.-min. sci. diss. Kazan, 219 p. (In Russ.)

14. Nurgalieva N.G. Anikina E.A., Khasanova N.M. (2017). The structure of the Tournaisian oil-bearing limestones of the southern slope of the South Tatar arch according to the data of petrophysical and geochemical studies. Neftyanoe khozyaistvo = Oil industry, 2, pp. 46-48. (In Russ.) DOI: 10.24887/0028-2448-2017-2-46-48

15. Otamendia A.M., Díaz M., Costanzo-Álvarez V., Aldana M., Pilloud A. (2006). EPR stratigraphy applied to the study of two marine sedimentary sections in southwestern Venezuela. Physics of the Earth and Planetary Interiors, 154, pp. 243-254. DOI: 10.1016/j.pepi.2005.04.015

16. Productive bituminous strata of the Permian deposits of the Melekes depression and the South Tatar arch (1982). Ed. V.I. Troepol’skii, N.P. Lebedev. Kazan: KSU, 104 p. (In Russ.)

17. Ronov A.B. (1973). Evolution of rock composition and geochemical processes in the sedimentary shell of the Earth. Tr. GEOKHI, I(IY), pp. 28-44. (In Russ.)

18. Strakhov N.M. (1963). Types of lithogenesis and evolution in the history of the Earth. Moscow: Gosgeoltekhizdat, 535 p. (In Russ.)

19. Uspenskii B.V., Valeeva I.F. (2008). Geology of deposits of natural bitumen in the Republic of Tatarstan. Kazan: GART, 347 p. (In Russ.)

20. Votyakov S.L., Galeev A.A., Galakhova O.L., Leonova L.V., Il’inykh A.S. (2005). EPR as a method for studying the organic component of biogenic carbonate rocks (on the example of stromatolite-containing rocks of the Riphean of the Southern Urals). Ezhegodnik In-ta geologii i geokhimii URO RAN, pp. 39-47. (In Russ.)

21. Wertz, J.E., Bolton, J.R. (1975). Theory and practical applications of the EPR method. Trans. from Eng. M.G. Goldfeld; Ed. L.A. Blumenfeld. Moscow: Mir, 548 p. (In Russ.)


Review

For citations:


Mudarisova R.A., Volkov Yu.V., Khasanova N.M., Uspensky B.V. Carbonate reservoir rocks characterization of the Kazanian Stage of the Gorsky ultraviscous oil field by electron paramagnetic resonance method. Georesursy = Georesources. 2022;24(3):90-98. https://doi.org/10.18599/grs.2022.3.8

Views: 165


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1608-5043 (Print)
ISSN 1608-5078 (Online)