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Potential for improving the efficiency of carbonate oil deposits waterflooding with the use of controlled salinity technology (Smart water) at fields of Tatarstan Republic

https://doi.org/10.18599/grs.2023.4.6

Abstract

The article provides an overview of ionmodified waterflooding technology, also known as low salinity, controlled salinity, or Smart water. This technology is currently considered one of the most promising approaches in the development of oil deposits in carbonate reservoirs due to its economic efficiency and environmental safety.
The article discusses the main mechanisms and processes underlying ion-modified waterflooding and presents the results of laboratory studies conducted on core samples from foreign oil deposits. It includes an analysis of several studies, including contact angle measurements and core flooding experiments on core samples from oil deposits in carbonate reservoirs on the eastern side of the Melekess depression in the Republic of Tatarstan.
It is important to note that the Vereyian deposits explored in this article are not a typical example of test objects for ion-modified water injection. This is because they are characterized by a low reservoir temperature of 23 °C, which suggests that the efficiency of the technology would likely be lower compared to studies conducted abroad, where reservoir temperatures were significantly higher. For example, Darvish Sarvestani et al. studied reservoir conditions at 90 °C, Yousef et al. – reservoir temperature of 100 °C, and Austad et al. examined the Ekofisk field at 130 °C and the Volhall field at 90 °C in Norway.
However, as several studies have indicated, prolonged contact between rock samples and ion-modified water contributes to significant hydrophilization of the rock surface, as confirmed by contact angle measurements. The contact angle decreases from approximately 138.3° to 53.45° after exposure to ion-modified water.
Additionally, the core flooding experiment demonstrated a slight increase in the oil displacement coefficient, reaching 9.2%.
These findings suggest the potential for enhanced oil recovery by injecting Smart water into the Vereyian sediments, although further research is required to confirm the underlying mechanism.

About the Authors

Z. R. Saptarova
Kazan Federal University
Russian Federation

Zalina R. Saptarova – Engineer, Hard-to-Recover  Reserves Simulation Research and Educational Center,  Institute of Geology and Petroleum Technology

4 Bolshaya Krasnaya str., Kazan, 420111



A. A. Mamonov
University of Stavanger
Norway

Alexander A. Mamonov – Researcher, University of Stavanger

Norway, Stavanger, 4033



S. A. Usmanov
Kazan Federal University
Russian Federation

Sergey A. Usmanov – Deputy Director, Hard-to-Recover Reserves Simulation Research and Educational Center,  Institute of Geology and Petroleum Technology

4 Bolshaya Krasnaya str., Kazan, 420111



A. A. Lutfullin
Tatneft PJSC
Russian Federation

Azat A. Lutfullin – Cand. Sci. (Engineering), Deputy Head of the Department of Field Development

75 Lenin st., Almetyevsk, 423450



V. A. Sudakov
Kazan Federal University
Russian Federation

Vladislav A. Sudakov – Deputy Director of the Institute for Innovations, Director of Hard-to-Recover Reserves Simulation Research and Educational Center, Institute of Geology and Petroleum Technology

4 Bolshaya Krasnaya str., Kazan, 420111



M. S. Shipaeva
Kazan Federal University; Geoindiсator LLC
Russian Federation

Maria S. Shipaeva – Technical Director, Geoindikator LLC;
Engineer, Hard-to-Recover Reserves Simulation Research and Educational Center, Institute of Geology and Petroleum Technology

4 Bolshaya Krasnaya str., Kazan, 420111



A. A. Shakirov
Kazan Federal University; Geoindiсator LLC
Russian Federation

Artur A. Shakirov – General Director, Geoindikator JSC; Deputy Director, Hard-to-Recover Reserves Simulation Research and Educational Center, Institute of Geology and Petroleum Technology

4 Bolshaya Krasnaya str., Kazan, 420111



S. A. Sitnov
Kazan Federal University
Russian Federation

Sergey A. Sitnov – Cand. Sci. (Chemistry), Senior Research Assistant, Institute of Geology and Petroleum Technology

29, build. 1, Kremlevskaya st., Kazan, 420008



V. A. Derevyanko
Kazan Federal University
Russian Federation

Vadim K. Derevyanko – Engineer, Institute of Geology and Petroleum Technology

4 Bolshaya Krasnaya str., Kazan, 420111



References

1. Abbasi S., Khamehchi E. (2021). Investigation of permeability decline due to coupled precipitation/dissolution mechanism in carbonate rocks during low salinity co-water injection. Energy Reports, 7(2021), pp. 125–135. https://doi.org/10.1016/j.egyr.2020.11.169

2. Abdallah W., Buckley J.S., Carnegie A., Edwards J., Herold B., Fordham E. (2007). Fundamentals of wettability. Oilfield Review, 19(2), pp. 44–61.

3. Afekare D., Radonjic M. (2017). From Mineral Surfaces and Coreflood Experiments to Reservoir Implementations: Comprehensive Review of Low Salinity Water Flooding (LSWF). Energy Fuels, 31(12), pp. 13043–13062. https://doi.org/10.1021/acs.energyfuels.7b02730

4. Aghajanzade M.R., Ahmadi P., Sharifi M., Riazi M. (2019). Wettability Alteration of Oil-Wet Carbonate Reservoir using Silica-Based Nanofluid: An Experimental Approach. Journal of Petroleum Science and Engineering, (178), pp. 700–710. https://doi.org/10.1016/j.petrol.2019.03.059

5. Al-Attar H.H., Mahmoud M.Y., Zekri A.Y., Almehaideb R., Ghannam M. (2013). Low-salinity flooding in a selected carbonate reservoir: experimental approach. Journal of Petroleum Exploration and Production Technology, 3, pp. 139–149. https://doi.org/10.1007/s13202-013-0052-3

6. Austad T. (2013). Chapter 13 – Water-Based EOR in Carbonates and Sandstones: New Chemical Understanding of the EOR Potential Using “Smart water”. Sheng J.J. (Ed.). Enhanced Oil Recovery Field Case Studies, Gulf Prof. Publ., pp. 301–335. https://doi.org/10.1016/B978-0-12-386545-8.00013-0

7. Darvish Sarvestani A., Ayatollahi S., Bahari Moghaddam M. (2019). Smart water flooding performance in carbonate reservoirs: an experimental approach for tertiary oil recovery. Journal of Petroleum Exploration and Production Technology, 9, pp. 2643–2657. https://doi.org/10.1007/s13202-019-0650-9

8. Grishin P.A., Kovalev K.M., Fomkin A.V. (2015). Prospects of the ion modified water application for the carbonate reservoirs flooding. Neftyanoe khozyaistvo = Oil industry, (10), pp. 98–101. (In Russ.)

9. Ivanova A.A., Mitiurev N.A., Shilobreeva S.N., Cheremisin A.N. (2019). Experimental Methods for Studying the Wetting Propertiesof Oil Reservoirs: A Review. Fizika Zemli = Physics of the Earth, (3), pp. 135–149. (In Russ.)

10. https://doi.org/10.31857/S0002-333720193135-149 Jackson M., Al-Mahrouqi D., Vinogradov J. (2016). Zeta potential in oil-water-carbonate systems and its impact on oil recovery during controlled salinity water-flooding. Scientific Reports, (6), 37363. https://doi.org/10.1038/srep37363

11. Katende A., Sagala F. (2019). A Critical review of Low Salinity Water Flooding: Mechanism, Laboratory and Field Application. Journal of Molecular Liquids, 278, pp. 627–649. https://doi.org/10.1016/j.molliq.2019.01.037

12. Koochi M., Varfolomeev M., Shakirov A. (2020). Ion Modified Water Flooding in Low-Permeable Carbonates of Bashkirsky Formation in Russia-Tatarstan. European Association of Geoscientists & Engineers, Saint Petersburg, 2020, pp. 1–5. https://doi.org/10.3997/2214-4609.202053185

13. Kuznetsov A.M., Kuznetsov V.V., Bogdanovich N.N. (2011). On the question of preserving natural wettability of a well core. Neftyanoe khozyaistvo = Oil industry, (1), pp. 21–23. (In Russ.)

14. Mikhailov N.N., Motorova K.A., Sechina L.S. (2016). Geological factors of wettability of oil and gas reservoir rocks. Neftegaz. ru, (3). https://magazine.neftegaz.ru/articles/prikladnaya-nauka/626760-geologicheskie-faktorysmachivaemosti-porod-kollektorov-nefti-i-gaza/ (In Russ.)

15. Mjos J.E., Strand S., Puntervold T., Gaybaliyev H. (2018). Effect of Initial Wetting on Smart water Potential in Carbonates. SPE EOR Conference at Oil and Gas West Asia, Muscat, Oman, March 2018. SPE-190414-MS. https://doi.org/10.2118/190414-MS

16. Motorova K.A. (2017). Microstructural wettability of oil and gas reservoirs. Cand. geol. and min. sci. diss. Moscow: Gubkin Russian State University of Oil and Gas, 167 p. (In Russ.)

17. Piñerez Torrijos I.D., Mamonov A., Strand S., Puntervold T. (2020). The role of polar organic components in dynamic crude oil adsorption on sandstones and carbonates. CT&F – Ciencia, Tecnología & Futuro, 10(2), pp. 5–16. https://doi.org/10.29047/01225383.251

18. Rezaei Koochi M., Gubaydullin F.A (2018). Application of ion-modified water to enhance oil recovery from low-permeability carbonate reservoirs. Neftyanaya provintsiya, (2), pp. 100–109. (In Russ.) https://doi.org/10.25689/NP.2018.2.100-109

19. Rezaeidoust A., Puntervold T., Strand S., Austad T. (2009). Smart water as Wettability Modifier in Carbonate and Sandstone: A Discussion of Similarities/Differences in the Chemical Mechanisms. Energy & Fuels, 23(9), pp. 4479–4485. https://doi.org/10.1021/ef900185q

20. Sagbana P.L., Sarkodie K., Nkrumah W.A. (2022). A critical review of Carbonate reservoir wettability modification during low salinity waterflooding. Petroleum, 9(3), pp. 317–330. https://doi.org/10.1016/j.petlm.2022.01.006

21. Strand S., Puntervold T., Austad T. (2016). Water based EOR from Clastic Oil Reservoirs by Wettability Alteration: A Review of Chemical Aspects. Journal of Petroleum Science and Engineering, 146, pp. 1079–1091. https://doi.org/10.1016/j.petrol.2016.08.012

22. Tafur N., Mamonov A., Khan M.A.I., Soto A., Puntervold T., Strand S. (2023). Evaluation of Surface-Active Ionic Liquids in Smart water for Enhanced Oil Recovery in Carbonate Rocks. Energy & Fuels, 37(16), pp. 11730–11742. https://doi.org/10.1021/acs.energyfuels.3c01488

23. Treiber L.E., Owens W.W. (1972). A Laboratory Evaluation of the Wettability of Fifty Oil-Producing Reservoirs. SPE Journal, 12(6), pp. 531–540. https://doi.org/10.2118/3526-PA

24. Varfolomeev M., Rezaei Koochi M., Yuan Ch., Khayrtdinov R., Mustafin A., Glukhov M., Kadyrov R., Sudakov V., Usmanov S. (2022). Feasibility of Ion-Modified Water for Low Salinity Water Flooding: A Case Study for Ultra-High-Salinity Carbonate Reservoir in Akanskoe Oilfield Tatarstan, Russia. SPE Conference at Oman Petroleum & Energy Show, Muscat, Oman, March 2022. https://doi.org/10.2118/200046-MS

25. Yousef A.A., Al-Saleh, S., Al-Kaabi A., Al-Jawfi M. (2010). Laboratory Investigation of Novel Oil Recovery Method for Carbonate Reservoirs. Canadian Unconventional Resources and International Petroleum Conference, Calgary, Alberta, Canada, October 2010. https://doi.org/10.2118/137634-MS

26. Yousef A.A., Liu J., Blanchard G., Al-Saleh S., Al-Zahrani T., AlZahrani R., Al-Tammar H., Al-Mulhim N.(2012). SmartWater Flooding: Industry’s First Field Test in Carbonate Reservoirs. SPE Annual Technical Conference and Exhibition, San Antonio, Texas, USA, October 2012. https://doi.org/10.2118/159526-MS

27. Yu L., Standnes D., Skjæveland S. (2007). Wettability Alteration of Chalk by Sulphate Containing Water, Monitored by Contact Angle Measurement. International Symposium of the Society of Core Analysts, Calgary, Canada, September 2007. https://jgmaas.com/SCA/2007/SCA2007_01.pdf


Review

For citations:


Saptarova Z.R., Mamonov A.A., Usmanov S.A., Lutfullin A.A., Sudakov V.A., Shipaeva M.S., Shakirov A.A., Sitnov S.A., Derevyanko V.A. Potential for improving the efficiency of carbonate oil deposits waterflooding with the use of controlled salinity technology (Smart water) at fields of Tatarstan Republic. Georesursy = Georesources. 2023;25(4):92-105. (In Russ.) https://doi.org/10.18599/grs.2023.4.6

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