Repetition of the Void Space Structure of Achimov Sandstones of the East Urengoyskoye Field in Artificially Created Geometry of a Silicon Microfluidic Chip
https://doi.org/10.18599/grs.2025.1.2
Abstract
In this work, a unique technique for replicating the void structure of a low-permeability reservoir in a silicon microfluidic chip has been developed. This technique is qualitatively superior to all previous ones and provides full repeatability of key parameters of the void structure (permeability; pore size distribution; average channel diameter; channel tortuosity, macro- to microporosity ratio) from digital core data. Moreover, the developed technique allows to exactly copy the pore geometry of the core sample from micro-CT images and recreate it inside the microfluidic chip. Using this technique, three artificial void space structures were developed for three samples of Achimov sandstones with different permeability (0.38; 2.04 and 9.86 mD). The mineralogical composition of the prototype samples was determined by a set of lithological and mineralogical studies and a positive correlation between the intensity of carbonate cementation and the decrease in permeability was revealed. Most of the macropores in the studied sandstones are associated with leaching of feldspars, and micropores are confined mainly to clay minerals. The conducted set of studies on the present samples will make it possible to extend the results of future filtration tests to rocks with similar mineralogical characteristics and filtration-capacitance properties. A qualitatively new method of creating inhomogeneous wettability of artificially created void space structure inside the microfluidic chip was developed. This technique consists in a smooth displacement of formation water from the microchip structure by a hydrophobic agent, which modifies wettability on the surface of macropores and channels, but does not enter the micropore structure due to residual water, which is held inside the microporous structures by capillary forces. Thus, this work is the first to apply a comprehensive multidisciplinary approach to replicate the core void structure within a microfluidic chip. In the future, this technique will be improved so that the results of filtration tests on microfluidic chips will even more reliably reflect fluid movement within the reservoir.
About the Authors
М. R. LatypovaRussian Federation
Margarita R. Latypova, PhD (Geology and Mineralogy), postgraduate student, engineer of the I category
Faculty of Geology; Department of Regional Geology and Earth History; Skolkovo Innovation Centre
121205; 11 Sikorsky st.; 119234; 1 Leninskie Gory; Moscow
D. I. Pereponov
Russian Federation
Dmitrii I. Pereponov, Postgraduate student, Research scientist
Skolkovo Innovation Centre
121205; Build. 1, 30 Bolshoi Boulevard; Moscow
V. V. Kazaku
Russian Federation
Vitaly V. Kazaku, Postgraduate student, Research scientist
Skolkovo Innovation Centre
121205; Build. 1, 30 Bolshoi Boulevard; Moscow
А. Scerbacova
Saudi Arabia
Alexandra Scerbacova, PhD (Technical Sciences), Postdoc researcher
College of Petroleum Engineering & Geosciences; Center for Integrative Petroleum Research; Sustainable and Resilient Materials Lab
31261; Dhahran
I. G. Maryasev
Russian Federation
Igor G. Maryasev, Head of the sector
Geological research sector
121353; Office 45, 20 Skolkovskoe shosse; Moscow
R. А. Mukhin
Russian Federation
Roman A. Mukhin, Research scientist
121353; Office 45, 20 Skolkovskoe shosse; Moscow
Е. D. Shilov
Russian Federation
Evgeny D. Shilov, Research assistant, Technical Director
Skolkovo Innovation Centre
121205; Build. 1, 30 Bolshoi Boulevard; Moscow
А. N. Cheremisin
Russian Federation
Alexey N. Cheremisin, PhD (Technical Sciences), Professor, Deputy Director for Experimental Research, General Director
Centre for Oil and Gas Science and Engineering (Skoltech Petroleum); Skolkovo Innovation Centre
121205; Build. 1, 30 Bolshoi Boulevard; Moscow
V. L. Kosorukov
Russian Federation
Vladimir L. Kosorukov, Senior Lecturer
Faculty of Geology; Department of Oil and Gas Sedimentology and Marine Geology
119234; 1 Leninskie Gory; Moscow
V. V. Churkina
Russian Federation
Valeria V. Churkina, Leading engineer
Faculty of Geology; Department of Geology and Geochemistry of Combustible Fossils
119234; 1 Leninskie Gory; Moscow
М. А. Tarkhov
Russian Federation
Mikhail A. Tarkhov, PhD (Physical and Mathematical Sciences), Head of the Laboratory
Research Laboratory of Quantum Technologies (RLQ)
119334; 32A Leninsky ave.; Moscow
V. А. Shtinov
Russian Federation
Vladimir A. Shtinov, Head of Department
Hydrodynamic Modelling Department
450006; Build. 1, 86 Lenina st.; Ufa
Т. E. Nigmatullin
Russian Federation
Timur E. Nigmatullin, Head of Department
Well Workover Technologies Department
450006; Build. 1, 86 Lenina st.; Ufa
E. S. Batyrshin
Russian Federation
Eduard S. Batyrshin, Head of Laboratory
Innovative Research Laboratory
450006; Build. 1, 86 Lenina st.; Ufa
I. V. Samsonov
Russian Federation
Igor V. Samsonov, Head of Department
Field Development Department; Special Research Department
117997; 26/1 Sofiyskaya emb.; Novyy Urengoy
References
1. Ali M., Jha N. K. Al-Yaseri A., Zhang Y., Iglauer S., Sarmadivaleh M. (2021). Hydrogen wettability of quartz substrates exposed to organic acids; Implications for hydrogen geo-storage in sandstone reservoirs. Journal of Petroleum Science and Engineering, 207, 109081. doi: 10.1016/j.petrol.2021.109081
2. Amott E. (1959). Observations Relating to the Wettability of Porous Rock. Trans, 216, pp. 156–162. doi: 10.2118/1167-G
3. Bartell F.E., Osterhof J.J. 1927. Determination of the Wettability of a Solid by a Liquid. Ind. Eng. Chem., 19(11), pp. 1277–1280.
4. Bera B., Mitra S.K., Vick D. (2011). Understanding the micro structure of Berea Sandstone by the simultaneous use of micro-computed tomography (micro-CT) and focused ion beam-scanning electron microscopy (FIB-SEM). Micron, 42(5), pp. 412–418. doi: 10.1016/j.micron.2010.12.002
5. Bera B., Gunda N.S.K., Mitra S.K., Vick D. (2012). Characterization of Nanometer-Scale Porosity in Reservoir Carbonate Rock by Focused Ion Beam–Scanning Electron Microscopy. Microscopy and Microanalysis, 18(01), pp. 171–178. doi: 10.1017/s1431927611012505
6. Beucher S., Lantuejoul C. (1979). Use of watersheds in contour detection. International Workshop on Image Processing, Rennes, France, pp. 2.1–2.12.
7. Beucher, S. (1991). The watershed transformation applied to image segmentation. Conference on Signal and Image Processing in Microscopy and Microanalysis, Cambridge, UK, pp. 299–314.
8. Beucher S., Meyer F. (1993). The morphological approach to segmentation: the watershed transformation. Mathematical Morphology in Image Processing, 12, pp. 433–481.
9. Bobek J.E., Mattax C.C., Denekas M.O. (1958). Reservoir rock wettability-its significance and evaluation. Transactions of the AIME, 213(1), pp. 155–160. doi: 10.2118/895-G
10. Buchgraber M., Clemens T., Castanier L.M., Kovscek A.R. (2011). A Microvisual Study of the Displacement of Viscous Oil by Polymer Solutions. SPE Reserv Eval Eng., 14(03), pp. 269–280.
11. Decision of the 5<sup>th</sup> Interdepartmental Regional Stratigraphic Meeting on Mesozoic Deposits of the West Siberian Plain (1991). Editor: I.I. Nesterov; deputy editors: V.S. Bochkarev, Y.V. Braduchan; editors: N.A. Belousova, V.I. Ilyina, A.M. Kazakov et al. Tyumen: ZapSib-NIIGNI, 54 p. (In Russ.)
12. Dorhjie, D.B., Pereponov, D., Aminev, T., Gimazov, A., Khamidullin, D., Kuporosov, D., Tarkhov, M., Rykov, A., Filippov, I., Mukhina, E. and Shilov, E. (2024). A Microfluidic and Numerical Analysis of Non-equilibrium Phase Behavior of Gas Condensates. Scientific Reports, 14(1), p. 9500. doi: 10.1038/s41598-024-59972-x
13. Gunde A.C., Bera B., Mitra S.K. (2010). Investigation of water and COsub>2</sub> (carbon dioxide) flooding using micro-CT (micro-computed tomography) images of Berea sandstone core using finite element simulations. Energy, 35(12), pp. 5209–5216. doi: 10.1016/j.energy.2010.07.045
14. Gunde K.N.S., Bera B., Karadimitriou N.K., Mitra S.K., Hassanizadeh S.M. (2011). Reservoir-on-a-Chip (ROC): A new paradigm in reservoir engineering. Lab on a Chip, 11(22), pp. 3785–3792. doi: 10.1039/C1LC20556K
15. Iglauer S., Ali M., Keshavarz A. (2021). Hydrogen wettability of sandstone reservoirs: Implications for hydrogen geo-storage. Geophysical Research Letters, 48(5). doi: 10.1029/2020GL090814
16. Johansen R.T., Dunning H.N. (1961). Relative wetting tendencies of crude oils by capillarimetric method. US Department of the Interior, Bureau of Mines, 5752.
17. Karadimitriou N.K. (2013). Two-phase flow experimental studies in micro-models. Utrecht Studies in Earth Sciences, 34 (Dissertation) 211 p.
18. Koh K.S., Chin J., China J., Chiang C.L. (2012). Quantitative Studies on PDMS-PDMS Interface Bonding with Piranha Solution and its Swelling Effect. Micromachines, 3, pp. 427–441. doi: 10.3390/mi3020427
19. Kurchikov A.R., Borodkin V.N., Nedosekin A.S., Zaboev K.O., Galinsky K.A. (2013). Lithological characteristics, reservoir properties and oil and gas bearing capacity of Lower Cretaceous sediments of the Nerutinskaya Depression and adjacent territories in the north of Western Siberia. Geology, Geophysics and Development of Oil and Gas Fields, 7, pp. 4–13. (In Russ.)
20. Kuznetsov, M.A., Ishkinov, S.M., Kuznetsova, T.I., Fakhretdinov, R.N., Yakimenko, G.H., Sidorov, R.V., Bobylev, O.A. (2017). Technology of limiting water inflows into producing wells. Petroleum Engineering. Development and exploitation of oil fields, 7, pp. 58–60. (In Russ.)
21. Lacey M., Hollis C., Oostrom M., Shokri N. (2017). Effects of Pore and Grain Size on Water and Polymer Flooding in Micromodels. Energy and Fuels, 31(9), pp. 9026–9034. doi: 10.1021/acs.energyfuels.7b01254
22. Lei W., Lu X., Liu F., Wang M. (2022). Non-monotonic wettability effects on displacement in heterogeneous porous media. J. Fluid Mech, (942 R5), doi: 10.1017/jfm.2022.386
23. Li T., Li Y., Zhang F., Liang N., Yin J., Zhao H., Yang Y., Chen B., Yang L. (2023). Piranha Solution-Assisted Surface Engineering Enables Silicon Nanocrystals with Superior Wettability and Lithium Storage. Crystals, 13(7), 1127. doi: 10.3390/cryst13071127
24. Lifton V.A. (2016). Microfluidics: an enabling screening technology for enhanced oil recovery (EOR). Lab on a Chip. Royal Society of Chemistry, pp. 1777–1796. doi: 10.1039/C6LC00318D
25. Mittal K.L. (2004). Contact Angle, Wettability and Adhesion, 3. CRC Press., 520 p.
26. Mooney R.W., Keenan A.G., Wood L.A. (1952). Adsorption of water vapor by montmorillonite. II. Effect of exchangeable ions and lattice swelling as measured by X-ray diffraction. Journal of the American Chemical Society, 74(6), pp. 1371–1374.
27. Moore, T.F., Slobod R.L. (1955). Displacement of Oil by Water-Effect of Wettability, Rate, and Viscosity on Recovery. Paper presented at the Fall Meeting of the Petroleum Branch of AIME, New Orleans, Louisiana, October, SPE-502-G. doi: 10.2118/502-G
28. Morris K.A., Shepperd C.M. (1982) The role of clay minerals in influencing porosity and permeability characteristics in the Bridport Sands of Wytch Farm, Dorset. Clay Minerals, 17(1), pp. 41–54. doi: 10.1180/claymin.1982.017.1.05
29. Mungan N. (1972). Relative permeability measurements using reservoir fluids. Society of Petroleum Engineers Journal, 12(5), pp. 398–402. doi: 10.2118/3427-PA
30. Nelson P.H. (2009). Pore-throat sizes in sandstones, tight sandstones, and shales. AAPG Bull, 93, pp. 329–340. doi: 10.1306/10240808059
31. Panikarovsky E.V., Panikarovsky V.V., Mansurova M.M., Listak M.V. (2020). Application of multistage hydraulic fracturing in the development of Achimov deposits of the Urengoyskoye field. Oil and Gas Studies, 2, pp. 38–48. (In Russ.) doi: 10.31660/0445-0108-2020-2-38-48
32. Pereponov D., Tarkhov M., Dorhjie D.B., Rykov A., Filippov I., Zenova E., Krutko V., Cheremisin A., Shilov E. (2023). Microfluidic Studies on Minimum Miscibility Pressure for n-Decane and COsub>2</sub>. Energies, 16, 4994. doi: 10.3390/en16134994
33. Pradhan S., Shaik I., Lagraauw R., Bikkina P. (2019). A semi-experimental procedure for the estimation of permeability of microfluidic pore network. MethodoX, 6, pp. 706–713. doi: 10.1016/j.mex.2019.03.025
34. Romm E.S. (1985). Structural models of rock pore space. Leningrad: Nedra, 240 p. (In Russ.)
35. Rushing J. A., Newsham K. E., Blasingame T. A. (2008). Rock typing—Keys to understanding productivity in tight gas sands. SPE Unconventional Resources Conference. Gas Technology Symposium, 114164. SPE-114164-MS. doi: 10.2118/114164-MS
36. Salathiel R. (1973). A. Oil recovery by surface film drainage in mixed-wettability rocks. Journal of petroleum technology, 25(10), pp. 1216–1224. doi: 10.2118/4104-PA
37. Scerbacova A., Pereponov D., Tarkhov, M., Kazaku, V., Rykov A., Filippov I., Zenova E., Krutko V., Cheremisin A., Evgeny S. (2023). Visualization of Surfactant Flooding in Tight Reservoir Using Microfluidics. Paper presented at the SPE - Europe Energy Conference featured at the 84<sup>th</sup> EAGE Annual Conference & Exhibition, Vienna, Austria. doi: 10.2118/214419-MS
38. Scherer M. (1987). Parameters Influencing Porosity in Sandstones: A Model for Sandstone Porosity Prediction. AAPG bulletin, 71(5), pp. 485–491. doi: 10.1306/94886ED9-1704-11D7-8645000102C1865D
39. Slobod R.L., Blum H.A. (1952). Method for Determining Wettability of Reservoir Rocks. J Pet Technol, 4 (1952), pp. 1–4. doi: 10.2118/137-G
40. Strassner J. E. (1968). Effect of pH on interfacial films and stability of crude oil-water emulsions. Journal of Petroleum Technology, 20(3), pp. 303–312. doi: 10.2118/1939-PA
41. Xi K., Cao Y.C., Jahren J., Zhu R.K., Bjorlykke K., Haile B.G., Zheng L.J., Hellevang H. (2015). Diagenesis and reservoir quality of the lower cretaceous quantou formation tight sandstones in the southern Songliao Basin, China. Sedimentary Geology, 330, pp. 90–107. doi: 10.1016/j.sedgeo.2015.10.007
42. Zahiri B., Sow P. K., Kung C.H., Merida W. (2017). Active Control over the Wettability from Superhydrophobic to Superhydrophilic by Electrochemically Altering the Oxidation State in a Low Voltage Range. Advanced Materials Interfaces, 1700121. doi: 10.1002/admi.201700121
Review
For citations:
Latypova М.R., Pereponov D.I., Kazaku V.V., Scerbacova А., Maryasev I.G., Mukhin R.А., Shilov Е.D., Cheremisin А.N., Kosorukov V.L., Churkina V.V., Tarkhov М.А., Shtinov V.А., Nigmatullin Т.E., Batyrshin E.S., Samsonov I.V. Repetition of the Void Space Structure of Achimov Sandstones of the East Urengoyskoye Field in Artificially Created Geometry of a Silicon Microfluidic Chip. Georesursy = Georesources. 2025;27(1):63-80. (In Russ.) https://doi.org/10.18599/grs.2025.1.2