Composition and Mineralogical Features of Ultramafic Rocks of Eastern Part of Southern Kraka Massif (South Urals)
https://doi.org/10.18599/grs.2024.4.9
Abstract
The paper presents new data on the structure and composition of ultramafic rocks in the eastern part of the South Kraka massif. It is shown that the studied area is composed predominantly of spinel peridotites, among which the main role belongs to lherzolites with a low content of clinopyroxene (2–5%) and harzburgites, among which lens-shaped and bandshaped inclusions of monomineral olivine rocks – dunites – are quite often observed. The leading role in the structure of the rocks belongs to high-Mg olivine (Fo87-94), a secondary role (2016). Nature of the lithospheric mantle beneath the Arabian Shield and genesis of Al-spinel micropods: Evidence from the mantle xenoliths of Harrat is played by high-Mg orthopyroxene (enstatite) and Ca-Mg clinopyroxene diopside. Rare minerals of the mantle stage are amphibole and plagioclase. A typical accessory mineral of ultramafic rocks is spinel, the composition of which varies from high-Al in lherzolites (Cr# = 0.16–0.3), to moderate-Al in harzburgites (Cr# = 0.3–0.55) and to high-Cr in dunites (Cr# = 0.6–0.85). Of the rare accessory minerals in the rocks, the following were identified: native copper, pentlandite, awaruite and PGM (laurite, irarsite, Os-Ir-Ru-alloys). The section of mantle ultramafic rocks of the Sargan Range completed its high-temperature evolution to the levels of the plagioclase peridotite facies, partly in the transition zone from spinel to plagioclase facies. An assessment of oxygen fugacity allows us to speak about more reducing conditions for the formation of rocks of the studied area compared to other similar formations of upper mantle origin and allows us to classify the studied ultramafic rocks as moderately depleted restites of the upper mantle under the riftogenic structure of the Paleo-Ural basin. The geochemical specialization of PGM also indicates a restite origin of ultramafic rocks. At the stage of cooling and tectonic transformations in the crust, ultramafic rocks underwent serpentinization.
About the Authors
D. E. SavelievRussian Federation
Dr. Sci. (Geology and Mineralogy), Chief Researcher.
16/2 K.Marks st., Ufa, 450077
A. I. Biembetov
Russian Federation
Director.
Burzyansky district,Republic of Bashkortostan, 453580
T. D. Shabutdinov
Russian Federation
Research Engineer.
16/2 K.Marks st., Ufa, 450077
A. A. Samigullin
Russian Federation
Junior Researcher.
16/2 K. Marks st., Ufa, 450077
R. A. Gataullin
Russian Federation
Junior Researcher.
16/2 K.Marks st., Ufa, 450077
References
1. Ahmed A.H., Moghazi A.K.M., Moufti M.R., Dawood Y.H., Ali K.A. (2016). Nature of the lithospheric mantle beneath the Arabian Shield and genesis of Al-spinel micropods: Evidence from the mantle xenoliths of Harrat Kishb, Western Saudi Arabia. Lithos, (240–243), pp. 119–139. https://doi.org/10.1016/j.lithos.2015.11.016
2. Arai S. (1994). Characterization of spinel peridotites by olivine-spinel compositional relationships: Review and interpretation. Chemical Geology, (113), pp. 191–204. https://doi.org/10.1016/0009-2541(94)90066-3
3. Arai S., Ishimaru S. (2008). Insights into petrological characteristics of the lithosphere of mantle wedge beneath arcs through peridotite xenoliths: a review. Journal of Petrology, (49), pp. 665–695. https://doi.org/10.1093/petrology/egm069
4. Ballhaus C., Berry R., Green D. (1991). High pressure experimental calibration of the olivineorthopyroxene-spinel oxygen geobarometer: Implication for the oxydation state of the upper mantle. Contribution to Mineralogy and Petrology, (107), pp. 27–40. https://doi.org/10.1007/BF00311183
5. Basylev B.A. (2003). Petrological and chemical evolution of mantle matter in lithosphere: comparisonal study of oceanic and alpine-type spinel peridotites. Dr. geol. and min. sci. diss. Moscow: GEOKHI, 371 p. (In Russ.)
6. Brey G.P., Köhler T. (1990). Geothermobarometry in 4-phase lherzolites: 2. New thermobarometers, and practical assessment of existing thermobarometers. Journal of Petrology, (31), pp. 1353–1378. https://doi.org/10.1093/petrology/31.6.1353
7. Chashchukhin I.S., Votyakov S.L. (2009). Behavior of iron-group elements, oxybarometry, and genesis of unique chromite deposits in the Kempirsai massif. Geology of Ore Deposits, 51, pp. 123–138. https://doi.org/10.1134/S1075701509020044
8. Coleman R.G. (1979). Ophiolites. Moscow: Mir, 262 p. (In Russ.)
9. Denisova E.A. (1990). Structure of the South Kraka ultrabasic massif. Izvestiya AN SSSR, Seriya geologicheskaya, 1, pp. 45–63. (In Russ.)
10. Dmitriev L.V., Ukhanov A.V., Sharaskin L.Y. (1972). On the question of the composition of the material of the upper mantle. Geokhimiya, 10, pp. 1155–1167. (In Russ.)
11. Fabries J. (1979). Spinel-olivine geothermometry in peridotites from ultramafic complexes. Contribution to Mineralogy and Petrology, (69), pp. 329–336. https://doi.org/10.1007/BF00372258
12. Farafontiev P.G. (1937). Geology and chromite deposits of the Kraka peridotite massifs in the South Urals. Ufa, BTSU (In Russ.)
13. Green D.H., Falloon T.J. (1998). Pyrolite: a Ringwood concept and its current expression. In: Jackson I (ed) The Earth’s mantle composition, Structure and Evolution 7. Cambridge University Press, Cambridge, pp. 311–378.
14. Hellebrand, E., Snow, J.E., Dick, H.J.B., Hofmann A. (2001). Coupled major and trace elements as indicators of the extent of melting in midocean-ridge peridotites. Nature, 410(6829), pp. 677–681. https://doi.org/10.1038/35070546
15. Kovalev S.G., Snachev V.I. (1998). Gyperbasite Kraka massifs (geology, petrology, metallogeny). Ufa: USC RAS, 104 p. (In Russ.)
16. Kvyatkovskii R.E. (1929). Geological description of the area between the Belaya river and the eastern slope of the Irendyk ridge. Ufa, BTSU (In Russ.)
17. Leake B.E., Woolley A.R., Arps C.E.S., Birch W.D., Gilbert M.C., Grice J.D., Hawthorne W.C., Kato A., Kisch K.J., Krivovichev V.G., Lithout K., Laird J., Mandarino J.A., Maresch W.V., Nickel E.A., Rock N.M.S., Schumacher J.C., Smith D.C., Stephenson N.C.N., Ungaretti L., Whittaker E.J.W., Youzhi G. (1997). Nomenclature of amphiboles; report of the subcommittee on amphiboles of the International Mineralogical Association commission on new minerals and mineral names. Canadian Mineralogist, (35), pp. 219–246. https://doi.org/10.1127/ejm/9/3/0623
18. Loginov V.P. (1933). Report on geological investigations in the area of peridotite massifs in 1932 (geological survey M 1:50 000). Ufa, BTSU (In Russ.)
19. Ono A. (1983). Fe-Mg partioning between spinel and olivine. J. Japan. Assoc. Min. Petr. Econ. Geol, (78), pp. 115–122. https://doi.org/10.2465/ganko1941.78.115
20. Ozawa K (1983). Evaluation of olivine-spinel geothermometry as an indicator of thermal history for peridotites. Contribution to Mineralogy and Petrology, (82), pp. 52–65. https://doi.org/10.1007/BF00371175
21. Parkinson I.J., Pearce J.A. (1998). Peridotites from the Izu–Bonin– Mariana forearc (ODP Leg 125): evidence for mantle melting and melt–mantle interaction in a supra-subduction zone setting. Journal of Petrology, (39), pp.1577–1618. https://doi.org/10.1093/petroj/39.9.1577
22. Pavlov N.V. (1949). Chemical composition of Cr-spinels in connection with the petrographic composition of rocks of ultramafic intrusions. Trudy instituta geologicheskikh nauk AN SSSR, 13(103), pp. 10–35. (In Russ.)
23. Puchkov V.N. (2010). Geology of the Urals and the Urals (current issues of stratigraphy, tectonics, geodynamics and metallogeny). Ufa: DizainPoligrafServis, 280 p. (In Russ.)
24. Putrika K.D. (2008). Thermometers and Barometers for Volcanic Systems. Reviews in Mineralogy and Geochemistry, (69), pp. 61–120. https://doi.org/10.2138/rmg.2008.69.3
25. Roeder R.L., Campbell I.H., Jamieson H.E. (1979). A Re-Evaluation of the Olivine-Spinel Geothermometer. Contribution to Mineralogy and Petrology, (68), pp. 325–334. https://doi.org/10.1007/BF00371554
26. Saveliev D.E. (2018). Kraka ultramafic massifs (the Southern Urals): features of structure and composition of peridotite-dunite-chromitite assemblages. Ufa: Bashkir encyclopedia, 204 p. (In Russ.)
27. Saveliev D.E., Gataullin R.A. (2021). Lherzolites of Aznagulovo area (the Southern Urals): composition and PTfO conditions of formation. Vestnik Akademii nauk po Respublike Bashkortostan, 3(103), pp. 15–25. (In Russ.)
28. Saveliev D.E., Gordeev V.Yu. (2019). Compositional variations of minerals in peridotite-dunite-chromitite assemblages of Uzyan Kraka massif (the Southern Urals). Geologiya. Izvestiya otdeleniya nauk o Zemle i prirodnykh resursov ANRB, 26, pp. 21–28. (In Russ.)
29. Saveliev D.E., Makatov D.K., Rakhimov I.R., Gataullin R.A., Shilovskikh V.V. (2022). Silicates from lherzolites in the south-eastern part of the Kempirsay massif as the matter source for giant chromitite deposits (the Southern Urals, Kazakhstan). Minerals, 8(12), p. 1061. https://doi.org/10.3390/min12081061
30. Saveliev D.E., Snachev V.I., Savelieva E.N., Bazhin E.A. (2008). Geology, petrochemistry and chromitite-bearing of gabbro-gyperbasite massifs of the Southern Urals. Ufa: DizainPoligrafServis, 320 p. (In Russ.)
31. Savelieva G.N. (1987). Gabbro-ultrabasic complexes of Uralian ophiolites and their analogues in the oceanic crust. Moscow: Nauka, 246 p. (In Russ.)
32. Savelieva G.N., Batanova V.G., Sobolev A.V. (2016). Pyroxene–Cr-spinel exsolution in mantle lherzolites of the Syum-Keu ophiolite massif (Arctic Urals). Russian Geology and Geophysics, 57, pp. 1419–1436. https://doi.org/10.1016/j.rgg.2015.12.001
33. Snachev V.I., Saveliev D.E., Rykus M.V. (2001). Petrochemical features of rocks and ores of Kraka gabbro-ultrabasic massifs. Ufa: BashGU, 212 p. (In Russ.)
34. Sobolev N.D. (1952). Ultrabasites of Greater Caucasus. Moscow: Gosgeolizdat, 240 p. (In Russ.)
35. Sokolov G.A. (1948). Chromites of Urals, their composition, crystallisation conditions and regularities of distribution. Moscow: Trudy of IGN AN SSSR, 12, 128 p. (In Russ.)
36. Tikhovidov S.F. (1932) Industrial and abbreviated preliminary geological report of the head of the I Chromite geological group of Bashgeoltrest on geological exploration work in the Kaginsky, Bashartsky and Khamitovsky regions of the republic for 1931. Ufa: BTGU. (In Russ.)
37. Varlakov A.S. (1986). Petrology of serpentinization processes of gyperbasites of folded regions. Sverdlovsk: UNTc AN SSSR, 224 p. (In Russ.)
38. Wells P.R.A. (1977). Pyroxene thermometry in simple and complex systems. Contribution to Mineralogy and Petrology, (62), pp. 129–139. https://doi.org/10.1007/BF00372872
39. Whitney D.L., Evans B.W. (2010). Abbreviations for names of rockforming minerals. Am. Mineral., (95), pp. 185–187. https://doi.org/10.2138/am.2010.3371
40. Wood B.J., Banno S. (1973). Garnet-orthopyroxene and orthopyroxeneclinopyroxene relationships in simple and complex systems. Contribution to Mineralogy and Petrology, (42), pp. 109–124. https://doi.org/10.1007/BF00371501
Review
For citations:
Saveliev D.E., Biembetov A.I., Shabutdinov T.D., Samigullin A.A., Gataullin R.A. Composition and Mineralogical Features of Ultramafic Rocks of Eastern Part of Southern Kraka Massif (South Urals). Georesursy = Georesources. 2024;26(4):248-259. (In Russ.) https://doi.org/10.18599/grs.2024.4.9