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PGM in chromitites of Kraka massifs (the Southern Urals): diversity and origin

https://doi.org/10.18599/grs.2024.4.8

Аннотация

The paper provides results of study of platinum group minerals (PGMs) from 18 ore occurrences and deposits of the Kraka massifs, most of these located in ultramafic rocks of the upper mantle section (15), and several occurrences in a crust-mantle transition complex (3). It is shown that chromitites in the upper mantle section have refractory geochemical specialization (Os-Ir-Ru), while chromitites of the transition complex typically contain Pt and Pd minerals. The highest concentrations of the platinum group elements (PGE) are observed in chromitites of the transition complex (up to 2500 ppb of the total PGE). However, minor amounts of chromitites at these sites do not allow us to consider this mineralization type as promising in practical terms. chromitites in the upper mantle section are about an order lower in PGE (50–200 ppb of the total PGE). Analysis of the obtained data suggests the following explanation for various PGM types identified. PGMs occurred in chromitites of the upper mantle section at two stages: 1) disulfides of the laurite-erlichmanite series and, to a lesser extent, Os-Ir-Ru alloys were formed within chromite grains in result of subsolidus processes in the upper mantle restite during solid-phase segregation of PGEs initially incorporated in the crystal lattice of chromite; 2) sulfoarsenides and other PGE compounds with basic metals and antimony were formed by hydrothermal processing of chromitites in crustal conditions. Pt and Pd minerals were produced by differentiation of magmatic melts separated from restite; they were completely or partly transformed under the impact of hydrothermal processes.

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Об авторе

D. E. Saveliev
Institute of Geology of the Ufa Federal Research Centre of the Russian Academy of Sciences
Россия

Dr. Sci. (Geology and Mineralogy), chief Researcher.

16/2 K.Marks st., Ufa, 450077



Список литературы

1. Auge T., Legendre O. (1994). Platinum-group element oxides from the Pirogues ophiolitic mineralization, New Caledonia: origin and significance. Economic Geology, 89, pp. 1454–1468. http://dx.doi.org/10.2113/gsecongeo.89.7.1454

2. Augé T. (1985). Platinum-group mineral inclusions in ophiolitic chromitite from the Vourinos complex. Greece. Can. Mineral., 23, pp. 163–171.

3. Augé T., Johan. Z (1988). Comparative study of chromite deposits from Troodos, Vourinos, North Oman and New caledonia ophiolites. In: Mineral Deposits within the European Community. Boissonnas J., Omenetto P. (eds) Springer-Verlag, Berlin, pp. 267–288. https://doi.org/10.1007/978-3-642-51858-4_15

4. Cabri L.J. (1981). The platinum-group minerals. In: Platinum-Group Elements: Mineralogy, Geology, Recovery. Cabri LJ (ed) Can Inst Min Metall Pet Spec 23, pp 84–15045.

5. Denisova E.A. (1990). Structure of the ultrabasic massif South Kraka (Southern Urals). Izvestiya AS USSR, ser. Geol, 1, pp. 45–63. (In Russ.)

6. Distler V., Kryachko V., Yudovskaya M. (2008). Ore petrology of chromite-PGE mineralization in the Kempirsai ophiolite complex. Mineral. Petrol., 92, pp. 31–58. https://doi.org/10.1007/s00710-007-0207-3

7. Farafontiev P.G. (1937). Geology and chromite deposits of the Kraka peridotite massifs in the South Urals. Ufa, BTSU (In Russ.)

8. Garuti G., Zaccarini F., Economou-Eliopoulos M. (1999). Paragenesis and composition of laurite from chromitites of Othrys (Greece): implications for Os–Ru fractionation in ophiolitic upper mantle of the Balkan peninsula. Miner Deposita, 34, pp. 312–319. https://doi.org/10.1007/s001260050206

9. Garuti G., Pushkarev E.V., Gottman I.A., Zaccarini F. (2021). chromitePGM Mineralization in the Lherzolite Mantle Tectonite of the Kraka Ophiolite complex (Southern Urals, Russia). Minerals, 11, 1287. https://doi.org/10.3390/min11111287

10. Gervilla F., Proenza J.A., Frei R., González-Jiménez J.M., Garrido C.J., Melgarejo J.C., Meibom A., Díaz-Martínez R., Lavaut W. (2005). Distribution of platinum-group elements and Os isotopes in chromite ores from MayaríBaracoa Ophiolilte Belt (eastern cuba). Contrib. Mineral. Petrol., 150, pp. 589–607. https://doi.org/10.1007/s00410-005-0039-2

11. Gijbels R.H., Millard H.T., Deborough G.A., Bartel A.J. (1974). Osmium, ruthenium, iridium and uranium in silicates and chromite from the eastern Bushveld complex, South Africa. Geochim. Cosmochim. Acta, 38, pp. 319–337. https://doi.org/10.1016/0016-7037(74)90113-6

12. González-Jiménez J.M., Griffin W.L., Gervilla F., Proenza J.A., O’Reilly S.Y., Pearson N.J. (2014). Chromitites in ophiolites: How, where, when, why? Part I. A review and new ideas on the origin and significance of platinumgroup minerals. Lithos, 189, pp. 127–139. http://dx.doi.org/10.1016/j.lithos.2013.06.016

13. Harris D.C., Cabri L.J. (1991). Nomenclature of platinum-group-element alloys: review and revision. Can. Mineral., 29, pp. 231–237.

14. Kazantseva T.T., Kamaletdinov M.A. (1969). On the allochthonous occurrence of hyperbasic massifs on the western slope of the Southern Urals. Doklady Earth Sciences, 189(5), pp. 1077–1080. (In Russ.)

15. Klochikhin A.V., Radchenko V.V., Buryachenko A.V. (1969). Geological structure of the northern part of the Zilair megasynclinorium and adjacent territories. Report. Ufa, BTSU (In Russ.)

16. Kovalev S.G., Snachev V.I. (1998). Gyperbasite Kraka massifs (geology, petrology, metallogeny). Ufa: USC RAS, 104 p. (In Russ.)

17. Kvyatkovskii R.E. (1929). Geological description of the area between the Belaya river and the eastern slope of the Irendyk ridge. Report. Ufa, BTSU (In Russ.)

18. Loginov V.P. (1933). Report on geological investigations in the area of peridotite massifs in 1932 (geological survey M 1:50 000). Ufa, BTSU (In Russ.)

19. Melcher F. (2000). Base metal – platinum-group element sulfides from the Urals and the Eastern Alps: characterization and significance for mineral systematics. Mineral. Petrol., 68, pp. 177–211. https://doi.org/10.1007/S007100050009

20. Menshikov V.I., Vlasova V.N., Lozhkin V.I., Sokolnikova Y.V. (2016). Determination of platinum-group elements in rocks by IcP-MS with external calibration after cation exchange separation of matrix elements by KU-2-8 resin. Analytics and Control, 20, pp. 190–201. (In Russ.) DOI: 10.15826/analitika.2016.20.3.003

21. Naldrett A.J., Cabri L.J. (1976). Ultramafic and related mafic rocks: their classification and genesis with special reference to the concentration of nickel sulfides and platinum-group elements. Econ. Geol., 71, pp. 1131–1158. https://doi.org/10.2113/gsecongeo.71.7.1131

22. O’Driscoll B., González-Jiménez J.M. (2016). Petrogenesis of the Platinum-Group Minerals. Reviews in Mineralogy & Geochemistry, 9(81), pp. 489–578. https://doi.org/10.2138/rmg.2016.81.09

23. Perevozchikov B.V., Bulykin L.D., Popov I.I., Orfanitskiy V.L., Andreev, M.I., Snachev V.I., Danilenko S.A., cherkasov V.L., chentsov A.M., Zharikova L.N., Klochko A.A. (2000). The register shows of chrome in the alpine-type peridotites of Urals. Perm, 474 p. (In Russ.)

24. Popova V.I., Belogub E.V., Rassomakhin M.A., Popov V.A., Khvorov P.V. (2022). Mineralogy of chromitites of mount Poklonnaya of the Karabash massif, South Urals. Mineralogy, 8(4), pp. 15–33. (In Russ.) DOI: 10.35597/2313-545X-2022-8-4-2

25. Rakhimov I.R., Saveliev D.E., Vishnevskiy A.V. (2021). Platinum metal mineralization of the South Urals magmatic complexes: geological and geodynamic characteristics of formations, problems of their genesis, and prospects. Geodynamics & Tectonophysics, 12(2), pp. 409–434. (In Russ.) DOI: 10.5800/GT-2021-12-2-0531

26. Saveliev D.E. (2018). Kraka ultramafic massifs (the Southern Urals): features of structure and composition of peridotite-dunite-chromitite assemblages. Ufa: Bashkir encyclopedia, 204 p. (In Russ.)

27. Saveliev D.E. (2022). Chromitite deposits of Ufaley ultramafic massif (South Urals). Georesursy = Georesources, 24(3), pp. 196–208. https://doi.org/10.18599/grs.2022.3.17

28. Saveliev D.E., Belogub E.V., Zaykov V.V., Snachev V.I., Kotlyarov V.A., Blinov I.A. (2015). First occurrences of PGE-mineralization in the Sredny Kraka ultramafic rocks (the Southern Urals). Doklady Earth Sciences, 460(2), pp. 103–105. https://doi.org/10.1134/S1028334X15020117

29. Saveliev D.E., Belogub E.V., Zaykov V.V., Snachev V.I., Kotlyarov V.A., Blinov I.A. (2014). PGE mineralization in ultramafic rocks of Central Kraka massif (South Urals). Rudy I metally = Ores and metals, pp. 33–42. (In Russ.)

30. Saveliev D.E., Gataullin R.A. (2023). Accessory mineralisations in lherzolites of Northern Kraka massif (South Urals). Georesursy = Georesources, 25(3), pp. 22–35. https://doi.org/10.18599/grs.2023.3.2

31. Saveliev D.E., Snachev V.I., Savelieva E.N., Bazhin E.A. (2008). Geology, petrochemistry and chromitite-bearing of gabbro-gyperbasite massifs of the Southern Urals. Ufa: DizainPoligrafServis, 320 p. (In Russ.)

32. Saveliev D.E., Makatov D.K., Vishnevskiy A.V., Gataullin R.A. (2023). Accessory Minerals in the chromitite Ores of Dzharlybutak Ore Group of Kempirsai Massif (Southern Urals, Kazakhstan): Clues for Ore Genesis. Minerals, 13, 263. https://doi.org/10.3390/min13020263

33. Savelieva G.N. (1987). Gabbro-ultramafic complexes of ophiolites of the Urals and their analogues in the modern oceanic crust. Moscow: Nauka. 246 p. (In Russ.)

34. Snachev V.I., Saveliev D.E., Rykus M.V. (2001). Petrochemical features of rocks and ores of Kraka gabbro-ultrabasic massifs. Ufa: BashGU, 212 p. (In Russ.)

35. Sokolov G.A. (1948). Chromites of Urals, their composition, crystallisation conditions and regularities of distribution. Moscow: Trudy of IGS AS USSR, 97(12), 128 p. (In Russ.)

36. Stockman H.W., Hlava P.F. (1984). Platinum-group minerals in Alpine chromitites from southwestern Oregon. Econ Geol, 79, pp. 492–508. https://doi.org/10.2113/gsecongeo.79.3.491

37. Tagle R., Berlin J. (2008) A database of chondrite analyses including platinum group elements, Ni, Co, Au, and Cr: Implications for the identification of chondritic projectiles. Meteoritics & Planetary Science, 43(3), pp. 541–559. https://doi.org/10.1111/j.1945-5100.2008.tb00671.x

38. Thalhammer, T.V. (1996). Association of PGE minerals in massive chromite ores of the Kempirsai ophiolitic complex (the Southern Urals): Evidence for mantle metasomatism. Zapiski RMO, 125(1), pp. 25–36. (In Russ.)

39. Tikhovidov S.F. (1932). Industrial and abbreviated preliminary geological report of the head of the I chromite geological group of Bashgeoltrest on geological exploration work in the Kaginsky, Bashartsky and Khamitovsky regions of the republic for 1931. Ufa: BTGU. (In Russ.)

40. Zaccarini F., Garuti G., Pushkarev E., Thalhammer O. (2018). Origin of platinum group minerals (PGM) inclusions in chromite deposits of the Urals. Minerals, 8, 379. https://doi.org/10.3390/min8090379


Рецензия

Для цитирования:


Saveliev D.E. PGM in chromitites of Kraka massifs (the Southern Urals): diversity and origin. Георесурсы. 2024;26(4):275-286. https://doi.org/10.18599/grs.2024.4.8

For citation:


Saveliev D.E. PGM in chromitites of Kraka massifs (the Southern Urals): diversity and origin. Georesursy = Georesources. 2024;26(4):275-286. https://doi.org/10.18599/grs.2024.4.8

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