Preview

Georesources

Advanced search

Peculiarities of Molecular Composition of Bitumoids in Bazhenov Deposits in the Northern Part of the West Siberian Platform

https://doi.org/10.18599/grs.2025.4.24

Abstract

The aim of the investigation is to study the molecular composition of hydrocarbon compounds (HC) in the pore space of the Bazhenov horizon rocks in the northern part of Western Siberia. The oil and gas source rock samples with mixed and continental organic matter from two wells G5 and G6 were investigated. The biomarker analysis of the bitumen from open, blocked, and closed pores showed significant differences in the composition of HC, which allowed to divide them into two groups. The presence of migrated HC in the open pores of the studied samples was determined by the differences in the biomarker parameter values characterizing the conditions of organic matter sedimentary conditions. The composition of migrated bitumen expresses the oxidative conditions of the parent predominantly continental organic matter sedimentation. Bitumen in the closed pores, on the contrary, was formed from predominantly marine OM in the reducing conditions. The maturity parameters of bitumen confirmed that the migrated HC have a different source. The values of Ts/(Ts+Tm), Ts/C30, 4MDBT/1MDBT, TAI/(I+II) for migrated bitumen from G5 and G6 wells characterize the stages of early-middle oil window respectively, closed pore HC – the stage of immature kerogen to early oil window.

About the Authors

M. S. Tikhonova
Lomonosov Moscow State University
Russian Federation

Margarita S. Tikhonova – Leading Engineer, Petroleum Geology Department

1 Leninskie gory, Moscow, 119234



A. G. Kalmykov
Lomonosov Moscow State University
Russian Federation

Anton G. Kalmykov – Cand. Sci. (Chemistry), Senior Researcher, Petroleum Geology Department

1 Leninskie gory, Moscow, 119234



O. N. Vidishcheva
Lomonosov Moscow State University
Russian Federation

Olesya N. Vidishcheva – Cand. Sci. (Geology and Mineralogy), Senior Researcher, Lithology and marine geology

1 Leninskie gory, Moscow, 119234



Yu. V. Kolosova
NOVATEK STC LLC
Russian Federation

Yuliya V. Kolosova – Senior Expert of the Department

7 Pozharnykh i spasateley St., Tyumen, 625031



L. Yu. Sigacheva
Lomonosov Moscow State University
Russian Federation

Lyubov Yu. Sigacheva – Postgraduate student, Petroleum Geology and Geochemistry Department

1 Leninskie gory, Moscow, 119234



T. V. Grigorenko
Lomonosov Moscow State University
Russian Federation

Tatiana V. Grigorenko – Postgraduate student, Petroleum Geology Department

1 Leninskie gory, Moscow, 119234



M. O. Kostyshina
Lomonosov Moscow State University
Russian Federation

Mariia O. Kostyshina – Postgraduate student, Petroleum Geology Department

1 Leninskie gory, Moscow, 119234



D. L. Gendel
NOVATEK STC LLC
Russian Federation

Danil L. Gendel – Head of the Department

7 Pozharnykh i spasateley St., Tyumen, 625031



E. M. Gol
ASPG-1 LLC
Russian Federation

Evgeniya M. Gol – Head of the Department

9 Slavyansky distric, Novy Urengoy, 629309



S. N. Reznik
ASPG-1 LLC
Russian Federation

Sergey N. Reznik – Cand. Sci. (Geology and Mineralogy), Chief Geologist

9 Slavyansky distric, Novy Urengoy, 629309



References

1. Balushkina N.S., Kalmykov G.A., Kiryuhina T.A., Korobova N.I., Korost D.V., Soboleva E.V., Stupakova, A.V., Fadeeva N.P., Hamidullin R.A., Shardanova T.A. (2013). Regularities of the structure of the Bazhenov horizon and the top of the Abalak Formation in connection with the prospects of oil production. Geologiya nefti i gaza = Geology of Oil and Gas, (3), pp. 48–61. (In Russ.)

2. Bilibin S.I., Kalmykov G.A., Ganichev D.I., Balushkina N.S. (2015). A model of oil-bearing rocks of the Bazhenov Formation. Geofizika, (3). pp. 5–14. (In Russ.)

3. Cassani F., Gallango O., Talukdar S., Vallejos C., & Ehrmann U. (1988). Methylphenanthrene maturity index of marine source rock extracts and crude oils from the Maracaibo Basin. Organic Geochemistry In Petroleum Exploration, pp. 73–80. https://doi.org/10.1016/B978-0-08-037236-5.50013-0

4. Connan J., Cassou A.M. (1980). Properties of gases and petroleum liquids derived from terrestrial kerogen at various maturation levels. Geochimica et Cosmochimica Acta, 44(1), pp. 1–23. https://doi.org/10.1016/0016-7037(80)90173-8

5. Didyk B.M., Simoneit B.R.T., Brassell S.T., Eglinton G. (1978). Organic geochemical indicators of palaeoenvironmental conditions of sedimentation. Nature, 272(5650), pp. 216–222. https://doi.org/10.1038/272216a0

6. Farrimond P., Bevan J.C., Bishop A.N. (1999). Tricyclic terpane maturity parameters: response to heating by an igneous intrusion. Organic Geochemistry, 30(8), pp. 1011–1019. https://doi.org/10.1016/S0146-6380(99)00091-1

7. Farrimond, P., Eglinton, G., Brassell, S. C., & Jenkyns, H. C. (1988). The Toarcian black shale event in northern Italy. Organic geochemistry, 13(4-6), pp. 823–832. https://doi.org/10.1016/0146-6380(88)90106-4

8. Kalmykov G. A., Balushkina N. S. (2017). Model of oil saturation in the pore space of rocks of the Bazhenov Formation in Western Siberia and its use for assessing resource potential. Moscow: GEOS. (In Russ.)

9. Kontorovich A.E., Ponomareva E.V., Burshtein L.M., Glinskikh V.N., Kim N.S., Kostyreva E.A., Pavlova M.A., Rodchenko A.P., Yan P.A. (2018). Distribution of organic matter in rocks of the Bazhenov horizon (West Siberia). Russ. Geol. Geophys., 59(3), pp. 285–298. https://doi.org/10.1016/j.rgg.2018.03.007

10. Kostenko O.V. (2014). Blocking character of distribution of high molecular weight bitumoid compounds in the pore system of the Bazhenov Formation (West Siberian basin). Oil and Gas Geology. Theory and practice, 9(1). (In Russ.) https://doi.org/10.17353/2070-5379/12_2014

11. Kruge M.A., Hubert J.F., Akes R.J., Meriney P.E. (1990). Biological markers in Lower Jurassic synrift lacustrine black shales, Hartford basin, Connecticut, USA. Organic Geochemistry, 15(3), pp. 281–289. https://doi.org/10.1016/0146-6380(90)90006-L

12. Liu H., Zhang M., Li X. (2014). Genesis study of high abundant 17α (H)-diahopanes in Lower Cretaceous lacustrine source rocks of the Lishu Fault Depression, Songliao Basin, Northeast China. Chinese Journal of Geochemistry, 33, pp. 201–206. https://doi.org/10.1007/s11631-014-0679-x

13. Mohnhoff D., Littke R., Krooss B.M., Weniger P. (2016). Flow-through extraction of oil and gas shales under controlled stress using organic solvents: Implications for organic matter-related porosity and permeability changes with thermal maturity. International Journal of Coal Geology, 157, pp. 84–99. https://doi.org/10.1016/j.coal.2015.09.010

14. Peters K.E., Moldowan J.M. (1991). Effects of source, thermal maturity, and biodegradation on the distribution and isomerization of homohopanes in petroleum. Organic geochemistry, 17(1), pp. 47–61. https://doi.org/10.1016/0146-6380(91)90039-M

15. Peters K.E., Walters C.C., Moldowan J.M. (2005). The biomarker guide. Cambridge university press, Vol 1. https://doi.org/10.1017/CBO9780511524868

16. Philp P. et al. (2021). Possible explanations for the predominance of tricyclic terpanes over pentacyclic terpanes in oils and rock extracts. Organic Geochemistry, 155, 104220. https://doi.org/10.1016/j.orggeochem.2021.104220

17. Price L.C., Clayton J.L. (1992). Extraction of whole versus ground source rocks: Fundamental petroleum geochemical implications including oil-source rock correlation. Geochimica et Cosmochimica Acta, 56(3), pp. 1213-1222. https://doi.org/10.1016/0016-7037(92)90057-P

18. Sajgó C.S., Maxwell J.R., Mackenzie A.S. (1983). Evaluation of fractionation effects during the early stages of primary migration. Organic Geochemistry, 5(2), pp. 65–73. https://doi.org/10.1016/0146-6380(83)90004-9

19. Stoupakova A.V., Kalmykov G.A., Fadeeva N.P., Bogomolov A.Kh., Kiryukhina T.A., Korobova N.I., Maltsev V.V., Pronina N.V., Sautkin R.S., Suslova A.A., Shardanova T.A. (2015). On the assessment of resources and reserves of shale oil. Bulletin of Moscow University. Series 4. Geology, 3, pp. 3–10. (In Russ.)

20. Stupakova A.V., Kalmykov G.A., Korobova N.I., Fadeeva N.P., Gatovsky Y.A., Suslova A.A., Sautkin R.S., Pronina N.V., Bolshakova M.A., Zavyalova A.P., Chupakhina V.V., Petrakova N.N., Miftakhova A.A. (2017). Domanic sediments of the Volga-Ural basin section types, formation conditions and prospects of oil and gas bearing capacity. Georesursy = Georesources, Special Issue, pp. 112–124. (In Russ.) http://doi.org/10.18599/grs.19.12

21. Tihonova M.S., Kalmykov A.G., Ivanova D.A., Vidishcheva O.V., Kalmykov G.A., Borisov R.S. (2021a). A model of the distribution of hydrocarbon compounds in the void space of the Bazhenov horizon. Bulletin of the Moscow University. Series 4. Geology, (6), pp. 98–109. (In Russ.)

22. Tikhonova M.S., Ivanova D.A., Kalmykov A.G., Borisov R.S., Kalmykov G.A. (2019). Methodology of stepwise extraction of rocks of high-carbondist formations for studying the component distribution of bitumoids and variability of their main geochemical parameters. Georesursy = Georesources, 21(2), pp. 172–182. (In Russ.) https://doi.org/10.18599/grs.2019.2.172-182

23. Tikhonova M.S.; Kalmykov A.G.; Ivanova D.A.; Vidischeva O.N.; Khomyachkova I.O.; Bolshakova M.A.; Ryazanova T.A.; Sautkin R.S.; Kalmykov G.A. (2021b). Variability of hydrocarbon compound composition in the Jurassic oil and gas maternal strata of the Kamennaya vertex of the Krasnoleninskiy vault (Western Siberia). Georesursy = Georesources, 23(2), 158–169. (In Russ.) https://doi.org/10.18599/grs.2021.2.16

24. Wilhelms A., Horstad I., Karlsen D. (1996). Sequential extraction—a useful tool for reservoir geochemistry. Organic Geochemistry, 24(12), pp. 1157–1172. https://doi.org/10.1016/S0146-6380(96)00100-3

25. Winters J.C., Williams J.A. (1969). Microbiological alteration of crude oil in the reservoir. Symposium on Petroleum Transformation in Geologic Environments, American Chemical Society, Division of Petroleum Chemistry, Paper PETR, 86, E22-E31.

26. Zhusheng J., Philp R. P., Lewis C. A. (1988). Fractionation of biological markers in crude oils during migration and the effects on correlation and maturation parameters. Organic Geochemistry In Petroleum Exploration, pp. 561–571. https://doi.org/10.1016/B978-0-08-037236-5.50062-2


Review

For citations:


Tikhonova M.S., Kalmykov A.G., Vidishcheva O.N., Kolosova Yu.V., Sigacheva L.Yu., Grigorenko T.V., Kostyshina M.O., Gendel D.L., Gol E.M., Reznik S.N. Peculiarities of Molecular Composition of Bitumoids in Bazhenov Deposits in the Northern Part of the West Siberian Platform. Georesursy = Georesources. 2025;27(4):163-176. (In Russ.) https://doi.org/10.18599/grs.2025.4.24

Views: 17


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1608-5043 (Print)
ISSN 1608-5078 (Online)